화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.117, No.44, 13893-13898, 2013
Delayed Response of Interfacial Tension in Propagating Chemical Waves of the Belousov-Zhabotinsky Reaction without Stirring
Time-resolved measurements of the interfacial tension of propagating chemical waves of the Belousov-Zhabotinsky reaction based on the iron complex catalysts were carried out without stirring by monitoring the frequency of capillary waves with the quasi-elastic laser scattering method. A delayed response of the interfacial tension with respect to absorption was found with the delay being ligand-dependent when the reaction was conducted at a liquid/liquid interface. This behavior is attributed to differences in adsorption activity of the hydrophobic metal catalyst. The delay time and the increase in interfacial tension were also reproduced by a model considering the rate constants of equilibrium adsorption.