A polymer gel electrolyte based on poly(methyl methacrylate-butyl acrylate-methacrylic acid)/polyethylene glycol 400 blend (P(MMA-BA-MAA)/PEG400) was successfully prepared by a simple and efficient procedure. The optimal ionic conductivity was achieved to be 3.12 mS cm(-1) at the temperature of 30 A degrees C when the electrolyte has the composition of 20 wt% P(MMA-BA-MAA)/PEG400 blend, 0.6 M NaI, and 0.06 M I-2 in the solvent gamma-butyrolactone (GBL). For tuning the ionic conductivity, various additives were introduced into the polymer gel electrolytes. The measured values of open circuit voltage, short circuit current, and total photovoltaic efficiency indicates that the adding of pyridine (PY) leads to better performance of the final dye-sensitized solar cells (DSSCs), while the adding of Guanidine thiocyante (GuSCN) leads to a worse one. 4-Tert-butylpyridine (TBP) additive takes a more complex effect on the performance of the final DSSCs. For polymer gel electrolyte with 0.5 M pyridine, the final fabricated dye-sensitized solar cell has overall energy conversion efficiency (eta) of 3.63 % (0.16 cm(2) active area) under AM 1.5 at irradiation of 100 mW cm(-2), which reached the level of the liquid electrolyte based device (eta = 3.83 % at 0.16 cm(2) active area). Meanwhile, this gel electrolyte exhibits well long-term stability. The mechanism analysis revealed the dependences of ionic conductivity on the concentration of polymer and NaI and the temperatures.