Journal of Adhesion Science and Technology, Vol.27, No.21, 2326-2339, 2013
Plasma-induced adhesion improvement of cotton/polypropylene-laminated fabrics
In this study, improvement in the adhesion strength of plasma-pretreated and laminated cotton/polypropylene (PP) fabrics using acrylic-based adhesive was investigated. Low-temperature, low-pressure oxygen plasma was utilized for surface modification of cotton/PP-laminated fabrics. Water absorption time was measured on plasma-treated cotton fabrics at different plasma power and treatment time conditions. The plasma conditions providing the fastest liquid absorption on the surface were selected and applied during plasma pretreatments. Surface wettability increased with increasing plasma power and plasma exposure time. Plasma-induced surface morphology changes were observed via Scanning Electron Microscope (SEM) images. X-ray Photoelectron Spectroscopy (XPS) analysis showed that oxygen content on the surface increased with plasma treatment, which contributed to the surface polarity and hydrophilicity. Peel bond strength results of untreated and plasma-treated samples were analyzed to determine the effect of plasma pretreatment process. Adhesion strength values of laminated samples, before washing and after 40 wash cycles, were determined by peel bond strength tests. Before washing, adhesion strength of plasma pre-treated, laminated samples was 28-60% higher than that of untreated laminated fabrics. After 40 wash cycles, adhesion strength of plasma pre-treated and laminated samples was about 40-69% higher than the untreated laminated fabrics. Peel bond strength values decreased with the increased number of wash cycles. Plasma pretreatment enhanced both the adhesion strength and washing resistance of laminated samples.
Keywords:adhesion strength;cotton;polypropylene;laminated fabric;oxygen plasma;surface modification;wettability