Liquefied petroleum gas (LPG) is a very important fuel and chemical feed stock as well; however, the hydrocarbon has been involved in many major fires and explosions. One of these accidents is boiling-liquid, expanding-vapor explosion (BLEVE). It is a phenomenon that results from the sudden release from confinement of a liquid at a temperature above its atmospheric-pressure boiling point. The sudden decrease in pressure results in the explosive vaporization of a fraction of the liquid and a cloud of vapor and mist with the accompanying blast effects. Most BLEVEs involve flammable liquids, and most BLEVE releases are ignited by a surrounding fire and result in a fireball. The primary objective of this paper is to develop a computer model in order to determine the thermal response of a spherical LPG tank involved in fire engulfment accidents. The assessment of the safety spacing between tanks was also discussed.