Industrial & Engineering Chemistry Research, Vol.52, No.44, 15541-15548, 2013
Renewable Polyurethane Microcapsules with Isosorbide Derivatives for Self-Healing Anticorrosion Coatings
Renewable polyurethane microcapsules containing isosorbide derivatives for self-repairing anticorrosion coatings were easily manufactured by interfacial polymerization of a dimer ester diisocyanate (DE-TDI) prepolymer derived from waste vegetable oil and 1,4-butanediol (BD) as a chain extender using ultrasonication. Two kinds of corrosion inhibitors were also synthesized by the ring-opening reaction of succinic anhydride (SA) or maleic anhydride (MA). Microcapsules having 11-38 mu m in diameter were obtained, and the typical core content of microcapsules was around 40-45 wt %. Salt spray tests used for evaluating self-healing anticorrosion coating systems showed significant rust retardancy, depending on the content of the isosorbide derivatives for corrosion control.