Conducting organic polymers have found two main kinds of application in electronics so far: as materials for construction of various devices and as selective layers in chemical sensors. In either case, interaction with ambient gases is critical. It may compromise the performance of a device based on conducting polymers, whereas it is beneficial in a sensor. Conductivity has been the primary property of interest. Work function-related to conductivity, but in principle a different property-has received only scant attention. Our aim here is to discuss the usability of conducting polymers in both types of electronic applications in light of these two parameters.