화학공학소재연구정보센터
Nature Materials, Vol.11, No.7, 590-594, 2012
Electrical control of the superconducting-to-insulating transition in graphene-metal hybrids
Graphene(1) is a sturdy and chemically inert material exhibiting an exposed two-dimensional electron gas of high mobility. These combined properties enable the design of graphene composites, based either on covalent(2) or non-covalent(3) coupling of adsorbates, or on stacked and multilayered heterostructures(4). These systems have shown tunable electronic properties such as bandgap engineering(3), reversible metal-insulating transition(2,4) or supramolecular spintronics(5). Tunable superconductivity is expected as well(6), but experimental realization is lacking. Here, we show experiments based on metal-graphene hybrid composites, enabling the tunable proximity coupling of an array of superconducting nanoparticles of tin onto a macroscopic graphene sheet. This material allows full electrical control of the superconductivity down to a strongly insulating state at low temperature. The observed gate control of superconductivity results from the combination of a proximity-induced superconductivity generated by the metallic nanoparticle array with the two-dimensional and tunable metallicity of graphene. The resulting hybrid material behaves, as a whole, like a granular superconductor showing universal transition threshold and localization of Cooper pairs in the insulating phase. This experiment sheds light on the emergence of superconductivity in inhomogeneous superconductors, and more generally, it demonstrates the potential of graphene as a versatile building block for the realization of superconducting materials.