Solvent extraction and supported liquid membrane (SLM) transport properties of Eu(III) from nitric acid feed conditions were investigated using several substituted diglycolamide (DGA) extractants such as N,N,NN-tetra-n-octyl diglycolamide (TODGA), N,N,NN-tetra(2-ethylhexyl) diglycolamide (T2EHDGA), N,N,NN-tetra-n-hexyl diglycolamide (THDGA), N,N,NN-tetra-n-pentyl diglycolamide (TPDGA), and N,N,NN-tetra-n-decyl diglycolamide (TDDGA). Effects of feed acidity and phase modifier composition on Eu(III) extraction were investigated using the DGAs and the nature of extracted species were ascertained by slope analysis method. The Eu(III) distribution ratio (D-Eu) values were found to decrease in the presence of iso-decanol. In general, the D-Eu values decreased with increased alkyl chain length of the DGA. The extracted species contained only 2 extractant molecules when TPDGA and TDDGA were used while for TODGA about four extractant molecules were found to be present in the extracted species. The supported liquid membrane transport of Eu(III) was studied under varying experimental conditions using the five DGA extractants. Transport studies using 0.1M DGA as the extractant suggested the trend as TDDGA>TODGA>T2EHDGA approximate to THDGA which significantly changed to TPDGA>THDGA>TODGA>TDDGA>T2EHDGA in the presence of 30% iso-decanol as the phase modifier. The permeability coefficient (P) values were also determined with membranes of varying pore sizes.