It is revealed that rigorous control of the size and surface of germanium nanoparticles allows fine color tuning of efficient fluorescence emission in the visible region. The spectral line widths of each emission were very narrow (<500 meV). Furthermore, the absolute fluorescence quantum yields of each emission were estimated to be 4-15%, which are high enough to be used as fluorescent labeling tags. In this study, a violet-light-emitting nanoparticle is demonstrated to be a new family of luminescent Ge. Such superior properties of fluorescence were observed from the fractions separated from one mother Ge nanoparticle sample by the fluorescent color using our developed combinatorial column technique. It is commonly believed that a broad spectral line width frequently observed from Ge nanoparticle appears because of an indirect band gap nature inherited even in nanostructures, but the present study argues that such a broad luminescence spectrum is expressed as an ensemble of different spectral lines and can be separated into the fractions emitting light in each wavelength region by the appropriate postsynthesis process.