Journal of Chemical and Engineering Data, Vol.42, No.2, 324-327, 1997
Isothermal Vapor-Liquid-Equilibria for the Systems 1-Chloro-1,1-Difluoroethane Plus Hydrogen-Fluoride, 1,1-Dichloro-1-Fluoroethane Plus Hydrogen-Fluoride, and Chlorodifluoromethane Plus Hydrogen-Fluoride
Isothermal vapor-liquid equilibria for the three binary systems (1-chloro-1,1-difluoroethane + hydrogen fluoride, 1,1-dichloro-1-fluoroethane + hydrogen fluoride, and chlorodinuoromethane + hydrogen fluoride) have been measured. The experimental data for the binary systems are correlated with the NRTL equation with the vapor-phase association model for the mixtures containing hydrogen nuoride, and the relevant parameters are presented. All of the systems form minimum boiling heterogeneous azeotropes.