Journal of Chemical and Engineering Data, Vol.41, No.5, 1176-1180, 1996
Isobaric Vapor-Liquid-Equilibria of the Water Plus 1-Propanol System at 30, 60, and 100 kPa
Isobaric vapor-liquid equilibria for the water + 1-propanol system are reported at 30, 60, and 100 kPa. The results were found to be thermodynamically consistent according to Van Ness-Byer-Gibbs, Kojima, and Wisniak methods. The system shows a minimum boiling azeotrope, and the azeotropic composition is scarcely shifted with pressure. Results were compared with literature values. The data were correlated with Margules, Van Laar, Wilson, NRTL, and UNIQUAC liquid-phase activity coefficient models.
Keywords:THERMODYNAMIC CONSISTENCY