The excess molar enthalpies at the temperature 298.15 K for ternary systems butan-1-ol + aniline + propanone and butan-2-ol + aniline + propanone and their constituent binary systems butan-1-ol + propanone and butan-2-ol + propanone, measured with an isothermal dilution calorimeter, are reported. The experimental results have been analyzed and compared with a polynomial equation and the UNIQUAC-associated solution model with binary and ternary additional parameters.