화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.19, No.4, 1365-1370, July, 2013
PVC based polyvinyl alcohol zinc oxide composite membrane: Synthesis and electrochemical characterization for heavy metal ions
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The polyvinyl chloride (PVC) based polyvinyl alcohol zinc oxide composite membrane was successfully prepared by solution casting technique. Membrane properties were studied in terms of water uptake, porosity, thickness, ion-exchange capacity and swelling. The physico-chemical characterization of the material was studied using Fourier transform infrared (FTIR) spectroscopy, thermogravimetry analysis (TGA), X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies. The important application of this composite ion-exchange membrane is in environmental separation of heavy metal ions transport. The increasing order of transport number of cation as HgCl2 < PbCl2 < CdCl2.
  1. Sen Gupta AK, in: Sen Gupta AK (Ed.), Ion Exchange Technology, Advances in Pollution Control, Technomic Pub. Co. Inc., Pennsylvania, 115 (1995)
  2. Argun ME, Journal of Hazardous Materials., 150, 587 (2008)
  3. Sata T, in: Kohovec J (Ed.), Macromolecules, VSP, Utrecht, the Netherlands, 451 (1992)
  4. Harisha RS, Hosamani KM, Keri RS, Nataraj SK, Aminabhavi TM, Desalination, 252(1-3), 75 (2010)
  5. Sekar M, Sakthi V, Rengaraj S, J. Colloid Interface Sci., 279(2), 307 (2004)
  6. Kumar M, Tripathi BP, Shahi VK, J. Membr. Sci., 340(1-2), 52 (2009)
  7. Islam M, Patel R, J. Hazard. Mater., 172(2-3), 707 (2009)
  8. Mohammadi T, Moheb A, Sadrzadeh M, Razmi A, Sep. Purif. Technol., 41(1), 73 (2005)
  9. Pyrzynska K, Trojanowicz M, Critical Reviews in Analytical Chemistry., 29, 313 (1999)
  10. Wiesner MR, Chellam S, Environmental Science and Technology., 33, 360A (1999)
  11. Gopal K, Tripathy SS, Bersillon JL, Dubey SP, J. Hazard. Mater., 140(1-2), 1 (2007)
  12. Strathmann H, in: Noble RD, Stern SA (Eds.), Membrane Separations Technology and Applications, Elsevier Science, Faculty of Chemical Technology, University of Twente, Enschede, Netherlands, 213 (1995)
  13. Nagarale RK, Gohil GS, Shahi VK, Advances in Colloid and Interface Science., 119, 97 (2006)
  14. Kumar M, Tripathi BP, Shahi VK, J. Membr. Sci., 340(1-2), 52 (2009)
  15. Shahi VK, et al., Reactive & Functional Polymers., 72, 115 (2012)
  16. Hussain AA, Nataraj SK, Abashar MEE, Al-Mutazb IS, Aminabhavi TM, J. Membr. Sci., 310(1-2), 321 (2008)
  17. Sata T, Sata T, Yang WK, J. Membr. Sci., 206(1-2), 31 (2002)
  18. Mohammad A, Inamuddin, Amin A, Naushad M, Eldesoky GE, Journal of Thermal Analysis and Calorimetry., http://dx.doi.org/10.1007/S10973-011-2169-2. (2012)
  19. Al-Othman ZA, Inamuddin, Naushad M, Chem. Eng. J., 169(1-3), 38 (2011)
  20. Khan AA, et al., Reactive & Functional Polymers., 63, 119 (2005)
  21. Khan AA, Khan A, Talanta., 72, 699 (2007)
  22. Khan MMA, Rafiuddin, Inamuddin, J. Ind. Eng. Chem., 18(4), 1391 (2012)
  23. ASTM D543-95, Standard particles for evaluating the resistance of plastics to chemical reagents, 27 (1998)
  24. Padaki M, Isloor AM, Belavadi G, Prabhu KN, Ind. Eng. Chem. Res., 50(11), 6528 (2011)
  25. Koter S, Piotrowski P, Kerres J, J. Membr. Sci., 153(1), 83 (1999)
  26. Titiloye JO, Hussain I, Journal of Colloid and Interface Science., 318, 50 (2008)
  27. Resina M, Macana´ s J, de Gyves J, Munˇ oz M, Journal of Membrane Science., 289, 150158 (2007)
  28. Nakamoto K, Infrared and Raman Spectra of Inorganic and Coordinate Compounds, Wiley-Interscience, New York (1986)
  29. Khan AA, Reactive & Functional Polymers., 66, 1649 (2006)
  30. Khan AA, Inamuddin, Alam MM, Mater. Res. Bull., 40(2), 289 (2005)
  31. Khan AA, Alam MM, Reactive and Functional Polymers., 55, 277 (2003)
  32. Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566 (2003)
  33. Choi JH, Moon SH, J. Membr. Sci., 191(1-2), 225 (2001)
  34. Schaep J, Vandecasteele C, J. Membr. Sci., 188(1), 129 (2001)
  35. Khan MMA, Rafiuddin, Desalination., 294, 74 (2012)
  36. Khan MMA, Rafiuddin, Materials Science and Engineering C., 32, 1210 (2012)
  37. Meyer K, Sievers JF, Helvetica Chimica Acta., 649, 665, 987, 19 (1936)
  38. Chou TJ, Tanioka A, J. Phys. Chem. B, 102(37), 7198 (1998)
  39. Matsumoto H, Tanioka A, Murata T, Higa M, Horiuchi K, J. Phys. Chem. B, 102(25), 5011 (1998)
  40. Chou TJ, Tanioka A, J. Colloid Interface Sci., 212(2), 293 (1999)