메조기공을 갖는 다양한 금속 산화물 촉매를 이용한 사이클로헥사놀의 탈수소화 반응

이은옥; 김명실; 김지만; Eunok Lee; Mingshi Jin; Ji Man Kim

Korean Chemical Engineering Research, Vol.51, No.4, 518-522, August, 2013

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메조기공을 갖는 다양한 금속 산화물 촉매를 이용한 사이클로헥사놀의 탈수소화 반응

Highly Ordered Mesoporous Metal Oxides as Catalysts for Dehydrogenation of Cyclohexanol

이은옥, 김명실, 김지만^†

성균관대학교 화학과, 440-746 경기도 수원시 장안구 서부로 2066

Eunok Lee, Mingshi Jin, and Ji Man Kim^†

Department of Chemistry, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon, Gyeonggi 440-746, Korea

E-mail:

초록

사이클로헥사논은 나일론의 단량체로 사용되는 카프로락탐의 원료로 중요한 중간체이며 사이클로헥사놀의 탈수소화 반응을 통해 합성된다. 본 연구에서는 탈수소화 반응에 적용하기 위한 촉매로 다양한 메조기공을 가진 금속 산화물(meso-WO3, meso-TiO2, meso-Fe2O3, meso-CuO, meso-SnO2, meso-NiO)을 나노 복제법에 의해 합성하였다. 그 결과 meso-WO3>>meso-Fe2O3>meso-SnO2>meso-TiO2>meso-NiO>meso-CuO 순서로 촉매 활성이 나타났으며, 그 중 meso-WO3가 가장 높은 촉매 활성을 보임을 알 수 있었다. 따라서 사이클로헥사놀을 이용한 탈수소화 반응에 meso-WO3의 폭넓은 응용 가능성을 확인하였다.

Cyclohexanone is important intermediate for the manufacture of caprolactam which is monomer of nylron. Cyclohexanone is generally produced by dehydrogenation reaction of cyclohexanol. In this study, highly mesoporous metal oxides such as meso-WO3, meso-TiO2, meso-Fe2O3, meso-CuO, meso-SnO2 and meso-NiO were synthesized using mesoporous silica KIT-6 as a hard template via nano-replication method for dehydrogenation of cyclohexanol. The overall conversion of cyclohexanol followed a general order: meso-WO3 >> meso-Fe2O3 > meso-SnO2 > meso-TiO2 > meso-NiO > meso-CuO. In particular, meso-WO3 significantly showed higher activity than the other mesoporous metal oxides. Therefore, the meso-WO3 has wide range of application possibilities for dehydrogenation of cyclohexanol.

Keywords:Dehydrogenation;Cyclohexanone;Mesoporous Metal Oxide;Nano-Replication

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[2] Jeon GS, Chung JS, Korean. J. Chem. Eng., 49, 14 (1997)

[3] Samanta S, Mal NK, Manna A, Bhaumik A, Appl. Catal. A: Gen., 157, 273 (2004)

[4] Gao R, Dai WL, Yang X, Li H, Fan K, Appl. Catal. A: Gen., 138, 332 (2007)

[5] Djinovic P, Batista J, Levec J, Pintar A, Appl. Catal. A: Gen., 156, 364 (2009)

[6] Fridman VZ, Davydov AA, J. Catal., 195(1), 20 (2000)

[7] Popova M, Szegedi A, Lazar K, Dimitrova A, Catal. Lett., 1288, 141 (2011)

[8] Xu Y, Liu S, Wang L, Xie M, Guo X, Catal. Lett., 135, 30 (1995)

[9] Blasco T, Lopez Nieto JM, Appl. Catal. A: Gen., 117, 157 (1997)

[10] Liu YM, Cao Y, Yi N, Feng WL, Dai WL, Yan SR, He HY, Fan KN, J. Catal., 417, 224 (2004)

[11] Solsona B, Blasco T, Lopez Nieto JM, Pena ML, Rey F, AVM, J. Catal., 443, 203 (2001)

[12] Taguchi A, Schuth F, Microporous Mesoporous Mater., 77, 1 (2005)

[13] Carreon MA, Guliants VV, Eur. J. Inorg. Chem., 27 (2005)

[14] Wang YQ, Yang CM, Schmidt W, Spliethoff B, Bill E, Schuth F, Adv. Mater., 17(1), 53 (2005)

[15] Lyons DM, Ryan KM, Morris MA, J.Mater. Chem., 12, 1207 (2002)

[16] Yu X, Xu Z, Han S, J. Porous Mat., 17, 99 (2010)

[17] Zhu KK, Yue B, Zhou WZ, He HY, Chem. Commun., 349 (2003)

[18] Valdes-Solis T, Fuertes AB, Mater. Res. Bull., 41(12), 2187 (2006)

[19] Shon JK, Kon SSG, Kim JM, Ko CH, Jin M, Lee YY, Hwang SH, Yoon JA, Kim JN, Chem. Commun., 650 (2009)