화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.37, No.4, 513-517, July, 2013
Export Citation
열 처리를 통한 그래핀/폴리벤족사진 전도성 복합 박막 제조
Preparation of Graphene/Polybenzoxazine Conductive Composite Thin Film through Thermal Treatment
고영수, 차지정1, 임진형1, †
  • 공주대학교 천안공과대학 화학공학부
  • 1공주대학교 천안공과대학 신소재공학부
Young Soo Ko, Ji-Jung Cha1, and Jin-Heong Yim1, †
  • Department of Chemical Engineering, Kongju National University, Budeadong 275, Cheonan, Chungnam 330-717, Korea
  • 1Division of Advanced Materials Engineering, Kongju National University, Budeadong 275, Cheonan, Chungnam 330-717, Korea
E-mail:
초록
고내열성 고분자인 폴리벤족사진(PBZ)과 전도성 그래핀을 혼성화시켜 새로운 전도성 복합박막을 제조하는 연구를 처음으로 수행하였다. 단순한 열처리 공정에 의해 동시에 그래핀 옥사이드와 벤족사진 단량체를 환원 및 경화를 시켜 기계적/전기적 특성이 크게 향상된 그래핀/PBZ 복합 박막을 제조하였다. 그래핀/PBZ 복합 박막의 화학/결정 구조 및 형태학적 미세구조 분석으로부터 약 3 wt%의 그래핀이 복합 박막에 들어가더라도 그래핀이 비교적 균일하게 분산된다는 것을 알 수 있었다. 본 연구를 통하여 PBZ박막의 기계적 물성 향상과 동시에 도전성을 부여하는 효과적인 경로를 제공할 수 있었다.
A novel conductive composite thin film was prepared for the first time by hybridization between polybenzoxazine(PBZ) having high heat resistance property and conductive graphene. Mechanically robust conductive graphene/PBZ composite thin films could effectively be prepared by a simple thermal treatment, which simultaneously induces reduction of graphene oxide (GO) and crosslinking reaction of benzoxazine monomer. Graphene sheets seem to be uniformly dispersed up to 3 wt% graphene content in the composite thin film as shown in the results of chemical/crystal structural and morphological analyses. This efficient route for making graphene/PBZ composite thin film would provide simultaneous improvement of mechanical property as well as electrical conductivity.
Keywords:graphene;graphene oxide;polybenzoxazine;composite;electrical conductivity.
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