Langmuir, Vol.29, No.13, 4366-4372, 2013
Improved Synthesis of Gold and Silver Nanoshells
Metallic nanoshells have been in evidence as multifunctional particles Silica for optical and biomedical applications. Their surface plasmon resonance can be nanoparticle tuned over the electromagnetic spectrum by simply adjusting the shell thickness. Obtaining these particles, however, is a complex and time-consuming process, which involves the preparation and functionalization of silica nanoparticles, synthesis of very small metallic nanoparticles seeds, attachment of these seeds to the silica core, and, finally, growing of the shells in a solution commonly referred as Kgold. Here we present synthetic modifications that allow metallic nanoshells to be obtained in a faster and highly reproducible manner. The main improved steps include a procedure for quick preparation of 2.3 +/- 0.5 nm gold particles and a faster approach to synthesize the silica cores. An investigation on the effect of the stirring speed on the shell growth showed that the optimal stirring speeds for gold and silver shells were 190 and 1500 rpm, respectively. In order to demonstrate the performance of the nanoshells fabricated by our method in a typical plasmonic application, particles on a glass slide was implemented. The immobilized nanoshells were used as substratesa method to immobilize these for the surface-enhanced Raman scattering from Nile Blue A.