N-Acylchitosan Porous Bead들의 제조 및 금속이온 흡착특성에 관한 연구

손석일; 장병권; 최규석

Journal of the Korean Industrial and Engineering Chemistry, Vol.3, No.1, 156-171, March, 1992

A Study on the Synthesis of N-Acylchitosan Porous Beads and Their Metal Ion Adsorption Characteristics

Chitin was isolated from crab shell. Chitosan, which was prepared by the deacetylation of chitin, was acylated to obtain N-acetyl(regenerated chitin), N-propionyl, N-butyryl, N-hexanoyl, N-decanoyl and N-maleated chitosans and their metal ion adsorption characteristics of N-acylchitosans were investigated. In order to enhance the adsorptivity, their porous beads were prepared and their adsorptivity with respect to the porosity and the adsorptivities for metal ions(Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺, Ag⁺)were investigated. Their metal ion adsorptivities were remarkably imporved compared to those of chitin. As the larger acyl groups were introduced, adsorptivity increased, but that of N-decanoyl chitosan showed some decrease because of steric hindrance of the bulky if-decanoyl group. N-Maleated chitosan containing carboxyl group showed highly improved adsorptivity, and N-acylchitosans showed the good selective adsorption in the mixed metal ions(Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺ and Ag⁺). They also showed excellent adsorption characteristics as chelating polymers.

[References]

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Maruka R, Suder BJ, Wightman JP, J. Appl. Polym. Sci., 27, 4827 (1982)
Kurita K, Sannan T, Iwakura Y, J. Appl. Polym. Sci., 23, 511 (1979)
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Asano T, Hayakawa H, Suzuki T, Proc. 1st Int. Conf. Chitin and Chitosan, 231 (1978)
Hirano S, Kondo Y, Nakzawa Y, Carbohyd. Res., 100, 431 (1982)
Sakaguchi T, Nakajima A, Proc. 2nd Int. Conf. Chitin and Chitosan, 1778 (1982)
Muzzarelli RAA, Tanfani F, Proc. 2nd Int. Conf. Chitin and Chitosan, 39 (1982)
Masri MS, Reuter FW, Friedman M, J. Appl. Polym. Sci., 18, 675 (1974)
Eiden CA, Jewell CA, Wightman JP, J. Appl. Polym. Sci., 25, 1587 (1980)
Tokura S, Nishi N, Tsutsumi A, Somorin O, Polym. J., 15, 485 (1983)
Okimasu S, Nippon Nogei Kakaku Kaishi, 32, 303 (1958)
Horton D, Just EK, Carbohydr. Res., 23, 173 (1973)
Sakaguci T, Horikoshi T, Hakagima A, Agric. Biol. Chem., 45(10), 2191 (1981)
Vigo T, Welch CM, Carbohyd. Res., 32, 331 (1974)
Muzzarelli RAA, Rocchetti R, Talanta, 21, 1137 (1974)
Kaifu K, Nishi N, Komai T, Polym. J., 13, 241 (1981)
Hirano S, Kondo S, Ohe Y, Polymer, 16, 622 (1975)
Somorin O, Nishi N, Tokura S, Polym. J., 11, 391 (1979)
Muzzarelli RAA, Tanfani F, Emanulli M, Mariotti S, Carbohydr. Res., 107, 199 (1982)
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Moore GK, Roberts GAF, Proc. 1st. Int. Conf. Chitin and Chitosan, 421 (1978)
Moore GK, Roberts GAF, Int. J. Biol. Macromol., 2, 115 (1980)
Moore GK, Roberts GAF, Int. J. Biol. Micromol., 3, 292 (1981)
Hirano S, Ohe Y, Polymer, 16, 22 (1975)
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Hirano S, Ohe Y, Agric. Biol. Chem., 39(6), 1337 (1975)
Hirano S, Ohe Y, Ono H, Carbohydr. Res., 47, 315 (1976)
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Hirano S, Agric. Biol. Chem., 42(10), 1939 (1978)
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[Referenced By]

[1] Mima S, Miya M, Iwamoto R, Yoshikawa S, J. Appl. Polym. Sci., 28, 1909 (1983)

[2] Maruka R, Suder BJ, Wightman JP, J. Appl. Polym. Sci., 27, 4827 (1982)

[3] Kurita K, Sannan T, Iwakura Y, J. Appl. Polym. Sci., 23, 511 (1979)

[4] Austin PR, Barrine CJ, Zikakis JP, Science, 212, 749 (1981)

[5] Asano T, Hayakawa H, Suzuki T, Proc. 1st Int. Conf. Chitin and Chitosan, 231 (1978)

[6] Hirano S, Kondo Y, Nakzawa Y, Carbohyd. Res., 100, 431 (1982)

[7] Sakaguchi T, Nakajima A, Proc. 2nd Int. Conf. Chitin and Chitosan, 1778 (1982)

[8] Muzzarelli RAA, Tanfani F, Proc. 2nd Int. Conf. Chitin and Chitosan, 39 (1982)

[9] Masri MS, Reuter FW, Friedman M, J. Appl. Polym. Sci., 18, 675 (1974)

[10] Eiden CA, Jewell CA, Wightman JP, J. Appl. Polym. Sci., 25, 1587 (1980)

[11] Tokura S, Nishi N, Tsutsumi A, Somorin O, Polym. J., 15, 485 (1983)

[12] Okimasu S, Nippon Nogei Kakaku Kaishi, 32, 303 (1958)

[13] Horton D, Just EK, Carbohydr. Res., 23, 173 (1973)

[14] Sakaguci T, Horikoshi T, Hakagima A, Agric. Biol. Chem., 45(10), 2191 (1981)

[15] Vigo T, Welch CM, Carbohyd. Res., 32, 331 (1974)

[16] Muzzarelli RAA, Rocchetti R, Talanta, 21, 1137 (1974)

[17] Kaifu K, Nishi N, Komai T, Polym. J., 13, 241 (1981)

[18] Hirano S, Kondo S, Ohe Y, Polymer, 16, 622 (1975)

[19] Somorin O, Nishi N, Tokura S, Polym. J., 11, 391 (1979)

[20] Muzzarelli RAA, Tanfani F, Emanulli M, Mariotti S, Carbohydr. Res., 107, 199 (1982)

[21] Karrer P, White SM, Helv. Chim. Acta, 13, 1105 (1930)

[22] Schorigin PP, Hait E, Ber., 68B, 971 (1935)

[23] Roseman S, Ludowieg J, J. Am. Chem. Soc., 76, 301 (1954)

[24] Baker BR, Schaube RE, J. Org. Chem., 19, 646 (1954)

[25] Baker SA, Foster AB, Stacey M, Webber JM, J. Chem. Soc., 2218 (1958)

[26] Hall LD, Yalpani M, Carbohydr. Res., 83, C5 (1980)

[27] Yamagucchi R, Arai Y, Itoh T, Hirano S, Carbohydr. Res., 88, 1972 (1980)

[28] Moore GK, Roberts GAF, Proc. 1st. Int. Conf. Chitin and Chitosan, 421 (1978)

[29] Moore GK, Roberts GAF, Int. J. Biol. Macromol., 2, 115 (1980)

[30] Moore GK, Roberts GAF, Int. J. Biol. Micromol., 3, 292 (1981)

[31] Hirano S, Ohe Y, Polymer, 16, 22 (1975)

[32] Hirano S, Ohe Y, Carbohydr. Res., 41, 61 (1975)

[33] Hirano S, Ohe Y, Agric. Biol. Chem., 39(6), 1337 (1975)

[34] Hirano S, Ohe Y, Ono H, Carbohydr. Res., 47, 315 (1976)

[35] Hirano S, Yamaguch R, Biopolymers, 5, 1685 (1976)

[36] Hirano S, Agric. Biol. Chem., 42(10), 1939 (1978)

[37] Hirano S, Tobetto K, Hasegawa M, Matsuda N, J. Biomed. Mater. Res., 14, 477 (1980)

[38] Hirano S, Tobetto K, J. Biomed. Mater. Res., 15, 903 (1981)

[39] Hirano S, Moriyasu T, Carbohyd. Res., 92, 323 (1981)

[40] Koshugi J, U.S. Patent, 4,336,070 (1982)

[41] Koshugi J, U.S. Patent, 4,401,807 (1983)

[42] Japan Patent, 昭 62-151403 (1987)

[43] Hirano S, Noishiki Y, J. Biomed. Mater. Res., 19, 413 (1985)

[44] Sirica AE, Woodman RJ, Fed. Proc., 29, 681 (1970)

[45] Sirica AE, Woodman RJ, J. Nat'l. Cancer Inst., 47, 377 (1971)

[46] Cho IW, Gong MS, Park SB, Polym.(Korea), 6(4), 228 (1982)

[47] Seo T, Kanbara T, Iijima T, Sen-I Gakkaishi, 42, 123 (1986)

[48] Seo T, Kanbara T, Iijima T, J. Appl. Polym. Sci., 36, 1443 (1988)

[49] Kusaoke H, Iso S, Hirose K, Sakurai T, Kimura K, Sen-I Gakkaishi, 43(11), 608 (1987)

[50] Hackman RH, J. Biol. Sci., 7, 168 (1954)

[51] Muzzarelli RAA, "Chitin," Pergamon Press, New York (1977)