화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.21, No.5, 484-492, May, 2013
DOI10.1007/s13233-013-1053-2  Export Citation
Fluorinated/non-fluorinated sulfonated polynaphthalimides as proton exchange membranes
Yang Song, Chang Liu, Dianfu Ren, Liwei Jing, Zhenhua Jiang, and Baijun Liu†
  • Alan G MacDiarmid Institute, Jilin University, Changchun, 130012, P. R. China
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Two -SO3H containing diamine monomers, 2,5-bis(4-amino-2-trifluoromethylphenoxy)benzenesulfonic acid and 2,5-bis(4-aminophenoxy)benzenesulfonic acid were successfully synthesized through a typical aromatic nucleophilic substitution reaction followed by a reduction reaction, respectively. Derived from the diamine monomers, two series of sulfonated naphthalic polyimides (polynaphthalimides) containing ether and ketone linkages were synthesized through a “one pot” polymerization reaction. Some properties including thermal stability, mechanical properties, water uptake, swelling dimensional ratio, methanol permeability, and proton conductivity were thoroughly investigated. Some exhibited attractive properties as proton exchange membranes. It was found that the fluorinated series (CF3-SPI-X) exhibited higher dimensional stability and lower methanol permeability in comparison with non-fluorinated ones (SPI-X) at the same -SO3H group content.
Keywords:fuel cells;proton exchange membranes;polyimides;sulfonation;stability
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