화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.3, 1014-1023, May, 2013
DOI10.1016/j.jiec.2012.11.025  Export Citation
Structural and thermal characterization of macro-branched functional terpolymer containing 8-hydroxyquinoline moieties with enhancing biocidal properties
Narendra Pal Singh Chauhan†
  • Department of Polymer Science, University College of Science, Mohan Lal Sukhadia University, Udaipur 313 001, Rajasthan, India
E-mail:
Novel polyfunctional acetyl and hydroxyl bearing functional terpolymer (HQFCA) derived from 8- hydroxyquinoline (HQ), 4-chloroacetophenone (CA) and formaldehyde (F) has been synthesized by complex condensation polymerization in the presence of an acid catalyst. The structure and morphology of terpolymer were elucidated by FTIR-ATR, one-dimensional NMR (1H NMR, 13C NMR and DEPT-135 experiment), two-dimensional NMR (HSQC and TOCSY), pyrolysis GC.MS, gel permeation chromatography (GPC), nitrogen absorption, and optical microscopy (OM). Principal pyrolysis products generated from HQFCA units were 8-hydroxy-5,6-dimethylquinoline, 8-hydroxy-2-methylquinoline and 4-chloroacetophenone. This reactive terpolymer can be used as synthons for exchange membrane preparation and biomedical coating applications.
Keywords:Polycondensation;Micro-structural elucidation;Py-(GC/MS);Specific surface area;Polymeric biocides
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