화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.30, No.5, 1131-1141, May, 2013
DOI10.1007/s11814-013-0014-y  Export Citation
Density, ultrasonic velocity, viscosity and their excess parameters of the binary mixtures of N,N-dimethylaniline+1-alkanols (C3-C5), +2-alkanols (C3-C4), +2-methyl-1-propanol, +2-methyl-2-propanol at 303.15K
Gowrisankar Manukonda, Venkateswarlu Ponneri1, Sivakumar Kasibhatta2, and Sivarambabu Sakamuri3, †
  • Department of Chemistry, J.K.C. College, Guntur 522006, India
  • 1Department of Chemistry, S.V. University, Tirupathi 517502, India
  • 2Department of Chemistry, S.V. Arts (U.G. & P.G) College (T.T.D’S), Tirupathi 517502, India
  • 3Research Supervisor in Chemistry, Acharya Nagarjuna University, Guntur, India
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The density, ultrasonic velocity of sound and viscosity of binary mixtures of N,N-dimethyl aniline (N,NDMA) with 1-propanol, +2-propanol, +1-butanol, +2-butanol, +1-pentanol, +2-methyl-1-propanol, +2-methyl-2-propanol were measured at 303.15 K. These experimental data have been used to calculate excess volume VE, excess ultrasonic speeds uE, excess intermolecular free length LfE, excess acoustic impedance ZE, excess isentropic compressibility κsE, deviation in viscosity Δη and excess Gibbs free energy of activation of viscous flow (G*E). The values of Lf Eand κsE are negative over the wide range of composition for all the binary mixtures, while the values of ZE are positive. These results have been used to discuss the nature of interaction between unlike molecules in terms of hydrogen bonding, dipole-dipole interaction, proton-acceptor interaction and dispersive forces. The viscosity data have been correlated using three equations: Grunberg and Nissan, Katti & Chaudhri and Hind et al. The excess/deviations were fitted by a Redlich-Kister equation and the results were analyzed in terms of specific interactions present in these mixtures.
Keywords:Ultrasonic Velocity;Viscosity;Density;Excess Thermodynamic Parameters
  1. Gowrisankar M, Rambabu K, Venkateswarlu P, Raman GK, Phys. Chem. Liq., 28, 29 (1994)
  2. Gowrisankar M, Sivarambabu S, Venkateswarlu P, Siva Kumar K, Bull. Korean Chem. Soc., 33, 1686 (2012)
  3. Gowrisankar M, Venkateswarlu P, Siva Kumar K, Sivarambabu S, J. Mol. Liq., 173, 172 (2012)
  4. Gowrisankar M, Venkateswarlu P, Siva Kumar K, Sivarambabu S, J. Soln. Chem., In press (2012)
  5. Das JK, Dash SK, Swain N, Swain BB, J. Mol. Liq., 81, 163 (1999)
  6. Roy MN, Sinha A, Sinha B, J. Soln.Chem., 34, 1311 (2005)
  7. Nikam PS, Shirsat LN, Hasan M, J. Chem. Eng. Data, 43(5), 732 (1998)
  8. Lomte SB, Bawa MJ, Lande MK, Arbad BR, J. Chem. Eng. Data, 54(1), 127 (2009)
  9. Weng WL, J. Chem. Eng. Data, 44(1), 63 (1999)
  10. Vadamalar R, Mani D, Balakrishnan R, Research J. Chem.Sci., 19, 79 (2011)
  11. Parveen S, Singh S, Shukla D, Singh KP, Gupta M, Shukla JP, Acta Phy., Polo., 116, 1011 (2009)
  12. Nain AK, Fluid Phase Equilib., 259(2), 218 (2007)
  13. Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)
  14. Palepu R, Joan O, Campell D, J. Chem. Eng. Data., 30, 355 (1985)
  15. Riddick JA, Bunger WB, Sakano TK, Organic solvents Physical properties and method of purifications, Wiley Interscience, New York, 2 (1986)
  16. Riggio R, Martinez HE, De Salas NZ, Can. J. Chem., 70, 2859 (1992)
  17. Krishnaiah A, Surendranath KN, J. Chem. Eng. Data, 41(5), 1012 (1996)
  18. Jacobson B, J. Chem. Phys., 20, 927 (1952)
  19. Grunberg L, Nissan AH, Mixture Law for Viscosity, Nature., 164, 799 (1949)
  20. Katti PK, Chaudhri MH, J. Chem. Eng. Data., 9, 442 (1964)
  21. Hind RK, McLaughlin E, A. R. Ubbelohde Trans Faraday Soc., 56, 328 (1960)
  22. Ramanujappa T, Bhavani JA, Raja Gopal E, Manohara Murthi N, Indian J. Pure Appl. Phys., 38, 301 (2000)
  23. Reddy Y, Naidu PS, Ravindra Prasad K, Indian J. Pure Appl.Phys., 32, 958 (1994)
  24. Sri Devi U, Samatha K, Visvanantasarma A, J. Pure Appl.Ultrasonics., 26, 1 (2004)
  25. Fort RJ, Moore WR, Trans Faraday Soc., 61, 2102 (1965)
  26. Nikam PS, Kapade VM, Mehdimhasan, Indian J. Pure Appl.Ultrasonics., 7, 16 (2000)
  27. Ranjith Kumar B, Sathyanarayana B, Indian J. Pure Appl. Phys., 47, 511 (2009)
  28. Ranjith Kumar B, Sathyanarayana B, Indian J. Pure Appl. Phys., 47A, 1026 (2008)
  29. Anil Kumar N, International J. Thermophy., 28, 1228 (2007)
  30. Nath J, Srivastava AK, Fluid Phase Equilib., 28, 97 (1986)
  31. Illoekhani H, Reddy KD, Rao MVP, Phys. Chem. Liq., 14, 181 (1985)
  32. Fort RJ, Moore WR, Trans Faraday Soc., 62, 1112 (1966)
  33. Gonzalez B, Dominguez A, Tojo J, J. Chem. Eng. Data, 49(6), 1590 (2004)
  34. Reed TM, Taylor TE, J. Phys. Chem., 63, 58 (1959)
  35. Ali A, Nain AK, Ind. J. Phys., 74B, 63 (2000)
  36. Kalra KC, Singh KC, Spah DC, J. Ind. Chem. Soc., 69, 138 (1992)