화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.3, No.1, 35-45, March, 1992
광촉매반응의 응용
Application of Photocatalysis
초록
촉매화학의 새로운 한 분야인 광촉매반응에 대한 관심은 계속적으로 증가하고 있다. 최근 광촉매 반응은 값싸고 재생 가능한 에너지원과 화학적으로 유용한 물질을 얻을 수 있는 새로운 방법으로 주목을 받게 되었다. 본고에서는 광촉매반응의 기본원리 그리고 여러가지 불균일계 및 균일계 광촉매반응을 소개한다. 또한 앞으로의 광촉매반응의 응용에 있어서의 문제점과 전망에 대해 알아본다.
The interest in photocatalysis, which is a new branch of catalysis, is steadily increasing. Recently photocatalysis is attracting considerable attention as new methods and processes for obtaining cheap and renewable sources of energy and for syntheses of chemically useful products. In this review article, the principles and some examples of heterogeneous and homogeneous photocatalyses are described. In addition, the problems yet to resolve and the prospect of application of photocatalysis are discussed.
  1. Formenti M, Teichner SF, Special Periodical Report Catal., 2, 87 (1978)
  2. Fujishima A, Honda K, Bull. Chem. Soc. Jpn., 44, 1148 (1971) 
  3. Fujishima A, Honda K, Nature, 238, 37 (1972) 
  4. Claesson S, Engstrom L, Solar Energy-Photochemical Conversion and Storage, National Swedish Board for Energy Source Development, Project No. 5562071 (1977)
  5. Connolly J, Proceedings of the Third International Conference on the Photo-chemical Conversion and Storage of Solar Energy, Boulder, Colorado (1980)
  6. Formenti M, Juillet F, Meriaudeau P, Teichner SJ, Chem. Tech., 1, 680 (1971)
  7. Childs LP, Ollis DF, J. Catal., 67, 35 (1981) 
  8. Djeghri N, Teichner SJ, J. Catal., 62, 99 (1980) 
  9. Wagner FT, Somorjai GA, Nature, 285, 559 (1980) 
  10. Halmann M, Zukerman K, "Homogeneous and Heterogeneous Photocatalysis," eds. E. Pelizzetti and N. Serpone, 521, Reidel, Dordrecht (1986)
  11. Kraeutler B, Bard AJ, J. Am. Chem. Soc., 100, 5985 (1978) 
  12. Frank SN, Bard AJ, J. Am. Chem. Soc., 99, 303 (1977) 
  13. Carey JH, Oliver BG, Water Poll. Res. J. Canada, 15, 157 (1980)
  14. Carey JH, Lawrence J, Tosine HM, Bull. Environ. Contamn. Toxicol., 16, 697 (1976) 
  15. Ollis DF, Environ. Sci. Technol., 19, 480 (1985) 
  16. Fox MA, Accounts Chem. Res., 16, 314 (1983) 
  17. Bickley RI, Specialist Periodical Report Catal., 5, 308 (1982)
  18. Somorjai GA, "Chemistry in Two Dimensions Surfaces," 551, Cornell University Press, Ithaca (1981)
  19. Meissner D, Memming R, Shuben L, Yesodharan S, Graetzel M, Ber. Bunsenges. Phys. Chem., 89, 121 (1985)
  20. Reber JF, "Photoelectrochemistry, Photocatalysis and Photoreactors," ed. H. Schiavello, 335, Reidel, Dordrecht (1985)
  21. Fox MA, "Topics in Current Chemistry, Electrochemistry 1," ed. E. Steckhan, 73, Springer-Verlag, Berlin (1987)
  22. Knox RS, Solid State Phys., 5, 1 (1963) 
  23. Kraeutler B, Bard AJ, J. Am. Chem. Soc., 100, 4317 (1978) 
  24. Reiche H, Dunn WW, Bard AJ, J. Phys. Chem., 83, 2248 (1979) 
  25. Bard AJ, J. Photochem., 10, 59 (1979) 
  26. Sato S, White JM, J. Am. Chem. Soc., 102, 7206 (1980) 
  27. Sato S, J. Catal., 92, 11 (1985) 
  28. Sakata T, Kawai T, Hashimoto K, Chem. Phys. Lett., 88, 50 (1982) 
  29. Tanaka K, Blyholder G, J. Phys. Chem., 75, 1037 (1971) 
  30. Cunningham J, Penny AL, J. Phys. Chem., 76, 2353 (1972) 
  31. Boonstra AH, Mutsaers CAHA, J. Chem. Soc., 79, 1940 (1975)
  32. Tanaka K, J. Phys. Chem., 78, 555 (1974) 
  33. Courbon H, Formenti M, Pichat P, J. Phys. Chem., 81, 550 (1977) 
  34. Djeghri N, Formenti M, Juillet F, Teichner SJ, Discuss. Faraday Soc., 58, 185 (1974) 
  35. Harvery PR, Rudham R, Ward S, Discuss. Faraday Soc., 79, 1381 (1983)
  36. Bickley RI, Munuera G, Stone FS, J. Catal., 31, 398 (1973) 
  37. Yoshida S, Magatani Y, Noda S, Funabiki T, J. Chem. Soc.-Chem. Commun., 601 (1981)
  38. Formenti M, Juillet F, Meriaudeau P, Teichner SJ, Vergnon P, J. Colloid Interface Sci., 39, 79 (1972) 
  39. Kogo K, Yoneyama H, Tamura H, J. Phys. Chem., 84, 1705 (1980) 
  40. Herrmann JM, Pichat P, J. Chem. Soc.-Faraday Trans., 76, 1138 (1980) 
  41. Matsumoto Y, Nagai H, Sato E, J. Phys. Chem., 86, 4664 (1982) 
  42. Kaluza U, Boehm HP, J. Catal., 22, 347 (1971) 
  43. McLeanand WR, Ritchie M, J. Appl. Chem., 15, 452 (1965)
  44. Wolkenstein T, Adv. Catal., 23, 157 (1973)
  45. Boonstra AH, Mutsaers CAHA, J. Phys. Chem., 79, 2025 (1979)
  46. Schrauzer GN, Guth TD, J. Am. Chem. Soc., 99, 7189 (1977) 
  47. Aurian-Brajeni B, Halmann M, Manassen J, Sol. Energy, 25, 165 (1980) 
  48. Kranovskii AA, Brin GP, Dokl. Akad. Nauk SSSR, 168, 1100 (1966)
  49. Iyake MM, Yoneyama H, Tamura H, Bull. Chem. Soc. Jpn., 50, 1492 (1977) 
  50. Yoneyama H, Nishimura N, Tamura H, J. Phys. Chem., 85, 268 (1981) 
  51. Nishimoto S, Ohtani B, Kajiwara H, Kagiya T, J. Chem. Soc.-Faraday Trans., 79, 2685 (1983) 
  52. Bulatov AV, Khidekel MI, Izu. Akad. Nauk SSSR Ser. Khim., 1902 (1976)
  53. VanDamma H, Hall WK, J. Am. Chem. Soc., 101, 4373 (1979) 
  54. Yeneyama H, Koizumi M, Tamura H, Bull. Chem. Soc. Jpn., 52, 3349 (1979) 
  55. Sato S, White JM, Chem. Phys. Lett., 72, 83 (1980) 
  56. Sato S, White JM, J. Catal., 69, 128 (1980)
  57. Sato S, New J. Chem., 12, 859 (1988)
  58. Kodama S, Yabuta M, Kubokawa K, Chem. Lett., 1671 (1982) 
  59. Anpo M, Tanahashi I, Yubokawa Y, J. Chem. Soc.-Faraday Trans., 78, 2121 (1982) 
  60. Sato S, White JM, J. Phys. Chem., 85, 336 (1981) 
  61. Sato S, White JM, Ind. Eng. Chem. Prod. Res. Dev., 19, 542 (1980) 
  62. Kawai T, Sakata T, J. Chem. Soc.-Chem. Commun., 694 (1980)
  63. Sakata T, Kawai T, Chem. Phys. Lett., 80, 341 (1981) 
  64. Pichat P, Herrman JM, Disdier J, Courbon H, Mozzanega MN, Neuv. J. Chim., 5, 627 (1981)
  65. Kawai T, Sakata T, Nature, 286, 474 (1980) 
  66. Sakata T, Kawai T, Nauv. J. Chim., 5, 279 (1981)
  67. Serpone N, Borgarello E, Graetzel M, J. Chem. Soc.-Chem. Commun., 342 (1984)
  68. Matsumura M, Saho Y, Tsubomura M, J. Phys. Chem., 87, 3807 (1983) 
  69. Keller P, Moradpour A, Amouyal E, Kagen H, Nouv. J. Chim., 4, 337 (1980)
  70. Kiwi J, Borgarello E, Pelizzetti E, Visca M, Graetzel M, Angew. Chem.-Int. Edit., 19, 646 (1980) 
  71. Kaneko M, Takabayashi N, Yamada A, Chem. Lett., 1647 (1982) 
  72. Shinoda S, Moriyama H, Kise Y, Saito Y, J. Chem. Soc.-Chem. Commun., 348 (1978)
  73. Reber JF, "Photoelectrochemistry, Photocatalysis and Photoreactors," ed. M. Schiavello, 329, Reidel, Dordrecht (1985)
  74. Borgarello E, Kiwi J, Graetzel M, Pelizzetti E, Visca M, J. Am. Chem. Soc., 104, 2996 (1982) 
  75. Kraeutler B, Bard AJ, J. Am. Chem. Soc., 100, 5985 (1978) 
  76. Kraeutler B, Bard AJ, J. Am. Chem. Soc., 99, 729 (1977)
  77. Reiche H, Bard AJ, J. Am. Chem. Soc., 101, 3127 (1979) 
  78. Kawai T, Fujii M, Kanbe S, Kawai S, The 5th International Conference on Photochemical Conversion and Storage of Solar Energy, Osaka (1984)
  79. Sakata T, "Homogeneous and Heterogeneous Photocatalysis," eds. E. Pelizzetti and N. Serpone 397, Reidel, Dordrecht (1986)
  80. Baykut F, Benlioglu G, Baykut, "Homogeneous and Heterogeneous Photocatalysis," eds. E. Pelizzetti and N. Serpone 161, Reidel, Dordrecht (1986)
  81. Kraeutler B, Reiche H, Bard AJ, Hocker RG, J. Polym. Sci., 17, 535 (1979)
  82. Nishimoto S, Ottani B, Yoshikawa T, Kagiya T, J. Am. Chem., 105, 7180 (1983) 
  83. Yanagida S, Azuma T, Kawakami H, Kizumoto H, Sakurai H, J. Chem. Soc.-Chem. Commun., 21 (1984)
  84. Mattews RW, Nature, 11, 23 (1984)
  85. Curran JJ, Domenich J, Jaffrezic-Renault N, Phlilppe R, J. Phys. Chem., 89, 957 (1985)