Journal of Materials Science, Vol.48, No.5, 1997-2001, 2013
Effect of Y-doping on the transport and magnetic properties of La0.5Sr0.5CoO3 and La0.7Sr0.3CoO3
The temperature variation of magnetization, resistivity, and thermoelectric power of undoped and Y-doped La0.7Sr0.3CoO3 and La0.5Sr0.5CoO3 samples have been investigated. Y-doping decreases the magnetization possibly due to the spin-state transition of Co ions. The low temperature conduction in (La1-y Y (y) )(0.7)Sr0.3CoO3 is consistent with the variable range hopping. With Y-doping, value of the Seebeck coefficient increases as Y-doping decreases bandwidth and increases distortion. Seebeck coefficient value also reflects that the orbital stability increases with Sr concentration.