Synthesis of organoclays and their application for the adsorption of phenolic compounds from aqueous solution

Van Noi Nguyen; Thi Dieu Cam Nguyen; Thanh Phuong Dao; Hung Thuan Tran; Dinh Bang Nguyen; Dae Hee Ahn

Journal of Industrial and Engineering Chemistry, Vol.19, No.2, 640-644, March, 2013

DOI10.1016/j.jiec.2012.09.018 Export Citation

Synthesis of organoclays and their application for the adsorption of phenolic compounds from aqueous solution

Van Noi Nguyen, Thi Dieu Cam Nguyen^{1, †}, Thanh Phuong Dao, Hung Thuan Tran², Dinh Bang Nguyen, and Dae Hee Ahn³

Faculty of Chemistry, Hanoi University of Science, Vietnam National University, Hanoi, Viet Nam, Vietnam
¹Faculty of Chemistry, Quy Nhon University, Viet Nam, Vietnam
²Advanced Materials Technology Center, National Center for Technological Progress, Hanoi, Viet Nam, Vietnam
³Department of Environmental Engineering and Biotechnology, Myongji University, Republic of Korea

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Organoclays were synthesized by exchanging inorganic cations between layers in Thanh Hoa bentonite using organic cations including benzylhexadecyldimethylammonium (BHDDM+), dimethyldioctadecylammonium (DMDOD+) and benzylstearyldimethylammonium (BSDM+). Inserting organic cations increases material interlayer distance significantly (from 15 Å to 40 Å ) and simultaneously enhances affinity of materials toward organic pollutants. The results show that adsorption capacity of organics on organoclays strongly depends on affinity between organic substances and ammonium cations rather than on interlayer distance of organoclays. This means that the sorption of organoclays for organic contaminants was significantly influenced by the nature of the surfactants added to the clay.

Keywords:Organoclays;Quaternary ammonium salts;Organic;Sorption

[References]

de Paiva LB, Morales AR, Valenzuela Dı´az FR, Applied Clay Science., 42, 8 (2008)
Wang XG, Lin KSK, Chan JCC, Cheng SF, J. Phys. Chem. B, 109(5), 1763 (2005)
Nayak PS, Singh BK, Desalination, 207(1-3), 71 (2007)
Yıldız N, Gonulsen R, Koyuncu H, Calımlı A, Colloids and Surfaces A., 260, 87 (2005)
Juang RS, Lin SH, Tsao KH, J. Colloid Interface Sci., 254(2), 234 (2002)
Esumi K, Matoba M, Yamanaka Y, Langmuir, 12(9), 2130 (1996)
Dabrowski A, Advances in Colloid and Interface Science., 93, 135 (2001)
Al-Asheh S, Banat F, Abu-Aitah L, Sep. Purif. Technol., 33(1), 1 (2003)
Bartelt-Hunt SL, Burns SE, Smith JA, J. Colloid Interface Sci., 266(2), 251 (2003)
Esumim K, Yoshida K, Torigoe K, Koide Y, Colloids and Surfaces A., 160, 247 (1999)
Kim JH, Shin WS, Song DI, Choi SJ, Korean J. Chem. Eng., 23(1), 63 (2006)
Chen B, Zhu L, Zhu J, Xing B, Environmental Science and Technology., 39, 6093 (2005)
Shen YH, Colloids and Surfaces A., 232, 143 (2004)
Othaman R, Susilo A, Habaki H, Egashira R, Asian Journal of Chemical Engineering., 9, 1 (2009)
Khenifi A, Bouberka Z, Sekrane F, Kameche M, Derriche Z, Adsorption., 13, 149 (2007)
Andini S, Cioffi R, Montagnaro F, Pisciotta F, Santoro L, Applied Clay Science., 31, 126 (2006)
Zhu L, Chen B, Shen X, Environmental Science and Technology., 34, 468 (2000)
APHA/AWWA/WEF, 20th ed., Washington, DC, USA (1998)
Hackett E, Manias E, Giannelis EP, J. Chem. Phys., 108(17), 7410 (1998)
Lagaly G, Gonzalez MF, Weiss A, Clay Minerals., 11, 173 (1976)
Kwolek T, Hodorowicz M, Stadnicka K, Czapkiewicz J, J. Colloid Interface Sci., 264(1), 14 (2003)
Lee JY, Lee HK, Mater. Chem. Phys., 85(2-3), 410 (2004)
Yilmaz N, Yapar S, Applied Clay Science., 27, 223 (2004)
Tang Y, Hu Y, Song L, Gui Z, Chen Z, Fan W, Polymer Degradation and Stability., 82, 127 (2003)
Wolf TA, Demirel T, Bauman RE, Journal of the Water Pollution Control Federation., 58, 68 (1986)
Xi Y, Ding Z, Hongping H, Spectrochimica Acta., A61, 515 (2005)
Yariv S, Thermochim. Acta, 274, 1 (1996)
Zhu J, He H, Zhu L, Wen X, Deng F, Journal of Colloid and Interface Science., 286, 39 (2005)
Zhao H, Nagy KL, Waples JS, Vance GF, Environmental Science and Technology., 34, 4822 (2000)
Vaia RA, Teukolsky RK, Giannelis EP, Chemistry of Materials., 6, 1017 (1994)

[Referenced By]

[1] de Paiva LB, Morales AR, Valenzuela Dı´az FR, Applied Clay Science., 42, 8 (2008)

[2] Wang XG, Lin KSK, Chan JCC, Cheng SF, J. Phys. Chem. B, 109(5), 1763 (2005)

[3] Nayak PS, Singh BK, Desalination, 207(1-3), 71 (2007)

[4] Yıldız N, Gonulsen R, Koyuncu H, Calımlı A, Colloids and Surfaces A., 260, 87 (2005)

[5] Juang RS, Lin SH, Tsao KH, J. Colloid Interface Sci., 254(2), 234 (2002)

[6] Esumi K, Matoba M, Yamanaka Y, Langmuir, 12(9), 2130 (1996)

[7] Dabrowski A, Advances in Colloid and Interface Science., 93, 135 (2001)

[8] Al-Asheh S, Banat F, Abu-Aitah L, Sep. Purif. Technol., 33(1), 1 (2003)

[9] Bartelt-Hunt SL, Burns SE, Smith JA, J. Colloid Interface Sci., 266(2), 251 (2003)

[10] Esumim K, Yoshida K, Torigoe K, Koide Y, Colloids and Surfaces A., 160, 247 (1999)

[11] Kim JH, Shin WS, Song DI, Choi SJ, Korean J. Chem. Eng., 23(1), 63 (2006)

[12] Chen B, Zhu L, Zhu J, Xing B, Environmental Science and Technology., 39, 6093 (2005)

[13] Shen YH, Colloids and Surfaces A., 232, 143 (2004)

[14] Othaman R, Susilo A, Habaki H, Egashira R, Asian Journal of Chemical Engineering., 9, 1 (2009)

[15] Khenifi A, Bouberka Z, Sekrane F, Kameche M, Derriche Z, Adsorption., 13, 149 (2007)

[16] Andini S, Cioffi R, Montagnaro F, Pisciotta F, Santoro L, Applied Clay Science., 31, 126 (2006)

[17] Zhu L, Chen B, Shen X, Environmental Science and Technology., 34, 468 (2000)

[18] APHA/AWWA/WEF, 20th ed., Washington, DC, USA (1998)

[19] Hackett E, Manias E, Giannelis EP, J. Chem. Phys., 108(17), 7410 (1998)

[20] Lagaly G, Gonzalez MF, Weiss A, Clay Minerals., 11, 173 (1976)

[21] Kwolek T, Hodorowicz M, Stadnicka K, Czapkiewicz J, J. Colloid Interface Sci., 264(1), 14 (2003)

[22] Lee JY, Lee HK, Mater. Chem. Phys., 85(2-3), 410 (2004)

[23] Yilmaz N, Yapar S, Applied Clay Science., 27, 223 (2004)

[24] Tang Y, Hu Y, Song L, Gui Z, Chen Z, Fan W, Polymer Degradation and Stability., 82, 127 (2003)

[25] Wolf TA, Demirel T, Bauman RE, Journal of the Water Pollution Control Federation., 58, 68 (1986)

[26] Xi Y, Ding Z, Hongping H, Spectrochimica Acta., A61, 515 (2005)

[27] Yariv S, Thermochim. Acta, 274, 1 (1996)

[28] Zhu J, He H, Zhu L, Wen X, Deng F, Journal of Colloid and Interface Science., 286, 39 (2005)

[29] Zhao H, Nagy KL, Waples JS, Vance GF, Environmental Science and Technology., 34, 4822 (2000)

[30] Vaia RA, Teukolsky RK, Giannelis EP, Chemistry of Materials., 6, 1017 (1994)