A new method for analysis of sunset yellow in food samples based on cloud point extraction prior to spectrophotometric determination

M.S. El-Shahawi; A. Hamza; A.A. Al-Sibaai; A.S. Bashammakh; H.M. Al-Saidi

Journal of Industrial and Engineering Chemistry, Vol.19, No.2, 529-535, March, 2013

DOI10.1016/j.jiec.2012.09.008 Export Citation

A new method for analysis of sunset yellow in food samples based on cloud point extraction prior to spectrophotometric determination

M.S. El-Shahawi^†, A. Hamza, A.A. Al-Sibaai, A.S. Bashammakh, and H.M. Al-Saidi¹

Department of Chemistry, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
¹University College, Department of Chemistry, Umm AL Qura University, Makkah, Saudi Arabia

E-mail:

A simple new micelle mediated preconcentration method was developed for analysis of sunset yellow (SY) prior to its spectrophotometric determination. The method was based upon cloud point extraction of the ion associate of SY and trioctylamine (TOA) in HCl.Triton X-100. In the surfactant phase the SY species react with TOA yielding hydrophobic ion associate of SY-ㆍTOA+. The distribution coefficient of SY between surfactant-rich phase and aqueous phase was approximately 104. Validation was tested by comparing the results with standard HPLC. Isotherm and thermodynamic parameters, chemical equilibrium, extraction constants and stiochiometry of the associate were assigned.

Keywords:Micelle-mediated cloud point extraction;Sunset yellow;Sorption isotherm;Thermodynamics;Chemical equilibria;Food stuffs

[References]

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Chen QC, Mou SF, Hou XP, Riviello JM, Ni ZM, Journal of Chromatography A., 827, 73 (1998)
Lo´ pez-de-AlbaN PL, Michelini-Rodriguez LI, Wro´ bel K, Amador-Herna´ ndez J, Analyst., 122, 1575 (1997)
Pourreza N, Elhami S, Analytica Chimica Acta., 596, 62 (2007)
Pourreza N, Rastegarzadeh S, Talanta., 77, 733 (2008)
Pourreza N, Rastegarzadeh S, Larki A, Food Chemistry., 126, 1465 (2011)
Ni Y, Bai J, Talanta., 44, 105 (1997)
Barros AA, Anto´ nio J, Rodrigues M, Electroanalysis., 3, 243 (1991)
Fuh MR, Chia KJ, Talanta., 56, 663 (2002)
Urquiza MP, Ferrer R, Beltrain JL, Journal of Chromatography A., 883, 277 (2000)
Hoodles RA, Pitman KG, Stewart TE, Thompson JM, Arnold JE, Journal of Chromatography A., 54, 393 (1971)
Urquiza MP, Part MD, Beltrain JI, Journal of Chromatography A., 871, 227 (2000)
de Almeida Bezerra M, Arruda MAZ, Ferreira SLC, Applied Spectroscopy Reviews., 40, 269 (2009)
Wang LL, Wang JQ, Zheng ZX, Xiao P, J. Hazard. Mater., 177(1-3), 114 (2010)
Santalad A, Srijaranai S, Burakham R, Glennon JD, Deming RL, Analytical and Bioanalytical Chemistry., 395, 1307 (2009)
Rangel-Yagui CO, Pessoa-Jr A, Blankschtein D, Brazilian Journal of Chemical Engineering., 21(4), 531 (2004)
Corti M, Minero C, Degiorgio V, Journal of Physical Chemistry., 88, 309 (1984)
Ulusoy HI, Gurkan R, Ulusoy S, Talanta., 88, 516 (2012)
An L, Deng J, Zhou L, Li H, Chen F, Wang H, Liu YT, J. Hazard. Mater., 175(1-3), 883 (2010)
Purkait MK, Vijar SS, Dasgupta S, De S, Dyes and Pigments., 63, 151 (2004)
Clint JH, Surfactants Aggregation, Hardbound edn., Springer (1992)
Sanz CP, Halko R, Ferrera ZS, Santana Rodriguez JJ, Analytica Chimica Acta., 524, 265 (2004)
Pinto CG, Pavon JLP, Cordero BM, Analytical Chemistry., 66, 874 (1994)
Shi Z, He J, Chang W, Talanta., 64, 401 (2004)
Vidotti EC, Costa WF, Oliveira CC, Talanta., 68, 516 (2006)
Capitan F, Capitan-Vallevy LF, Fernandez MD, de Orbe I, Avidad R, Analytica Chimica Acta., 331 (141)
Capitan-Vallevy LF, Fernandez MD, de Orbe I, Avidad R, Analyst., 120, 2421 (1995)
Lia W, Zhao W, Chen J, Yang M, Analytica Chimica Acta., 605, 41 (2007)
Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
Purkait MK, Banerjee S, Mewara S, DasGupta S, De S, Water Research., 39, 3885 (2005)
Kukusamude C, Santalad A, Boonchiangma S, Burakham R, Srijaranai S, Chailapakulb O, Talanta., 81, 486 (2010)
Somorjai GA, Introduction to Surface Chemistry and Catalysis, John Wiley & Sons, Inc., New York (1994)
Zhou Z, Zhao D, Wang J, Zhao W, Yang M, Journal of Chromatography A., 1216, 30 (2009)
Purkait MK, DasGupta S, De S, Desalination, 244(1-3), 130 (2009)
Purkait MK, DasGupta S, De S, J. Hazard. Mater., 137(2), 827 (2006)
Miller JC, Miller JN, Statistics for Analytical Chemistry, 4th edn., Ellis Horwood, New York, 115 (1994)
Minioti KS, Sakellariou CF, Thomaids NS, Analytica Chimica Acta., 583, 103 (2007)
Razmara RS, Daneshfar A, Sahrai R, J. Ind. Eng. Chem., 17(3), 533 (2011)
Ghoreishi SM, Behpour M, Golestaneh M, Food Chemistry., 132, 637 (2012)
Nevado JJB, Flores JR, Llerena MJV, Talanta., 44, 467 (1997)

[Referenced By]

[1] Ghorpade VM, Salunkhe SS, in: Maga JA, Tu AT (Eds.), Food Additives Toxicology, Marcel Dekker, New York, 179 (1995)

[2] Chen QC, Mou SF, Hou XP, Riviello JM, Ni ZM, Journal of Chromatography A., 827, 73 (1998)

[3] Lo´ pez-de-AlbaN PL, Michelini-Rodriguez LI, Wro´ bel K, Amador-Herna´ ndez J, Analyst., 122, 1575 (1997)

[4] Pourreza N, Elhami S, Analytica Chimica Acta., 596, 62 (2007)

[5] Pourreza N, Rastegarzadeh S, Talanta., 77, 733 (2008)

[6] Pourreza N, Rastegarzadeh S, Larki A, Food Chemistry., 126, 1465 (2011)

[7] Ni Y, Bai J, Talanta., 44, 105 (1997)

[8] Barros AA, Anto´ nio J, Rodrigues M, Electroanalysis., 3, 243 (1991)

[9] Fuh MR, Chia KJ, Talanta., 56, 663 (2002)

[10] Urquiza MP, Ferrer R, Beltrain JL, Journal of Chromatography A., 883, 277 (2000)

[11] Hoodles RA, Pitman KG, Stewart TE, Thompson JM, Arnold JE, Journal of Chromatography A., 54, 393 (1971)

[12] Urquiza MP, Part MD, Beltrain JI, Journal of Chromatography A., 871, 227 (2000)

[13] de Almeida Bezerra M, Arruda MAZ, Ferreira SLC, Applied Spectroscopy Reviews., 40, 269 (2009)

[14] Wang LL, Wang JQ, Zheng ZX, Xiao P, J. Hazard. Mater., 177(1-3), 114 (2010)

[15] Santalad A, Srijaranai S, Burakham R, Glennon JD, Deming RL, Analytical and Bioanalytical Chemistry., 395, 1307 (2009)

[16] Rangel-Yagui CO, Pessoa-Jr A, Blankschtein D, Brazilian Journal of Chemical Engineering., 21(4), 531 (2004)

[17] Corti M, Minero C, Degiorgio V, Journal of Physical Chemistry., 88, 309 (1984)

[18] Ulusoy HI, Gurkan R, Ulusoy S, Talanta., 88, 516 (2012)

[19] An L, Deng J, Zhou L, Li H, Chen F, Wang H, Liu YT, J. Hazard. Mater., 175(1-3), 883 (2010)

[20] Purkait MK, Vijar SS, Dasgupta S, De S, Dyes and Pigments., 63, 151 (2004)

[21] Clint JH, Surfactants Aggregation, Hardbound edn., Springer (1992)

[22] Sanz CP, Halko R, Ferrera ZS, Santana Rodriguez JJ, Analytica Chimica Acta., 524, 265 (2004)

[23] Pinto CG, Pavon JLP, Cordero BM, Analytical Chemistry., 66, 874 (1994)

[24] Shi Z, He J, Chang W, Talanta., 64, 401 (2004)

[25] Vidotti EC, Costa WF, Oliveira CC, Talanta., 68, 516 (2006)

[26] Capitan F, Capitan-Vallevy LF, Fernandez MD, de Orbe I, Avidad R, Analytica Chimica Acta., 331 (141)

[27] Capitan-Vallevy LF, Fernandez MD, de Orbe I, Avidad R, Analyst., 120, 2421 (1995)

[28] Lia W, Zhao W, Chen J, Yang M, Analytica Chimica Acta., 605, 41 (2007)

[29] Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)

[30] Purkait MK, Banerjee S, Mewara S, DasGupta S, De S, Water Research., 39, 3885 (2005)

[31] Kukusamude C, Santalad A, Boonchiangma S, Burakham R, Srijaranai S, Chailapakulb O, Talanta., 81, 486 (2010)

[32] Somorjai GA, Introduction to Surface Chemistry and Catalysis, John Wiley & Sons, Inc., New York (1994)

[33] Zhou Z, Zhao D, Wang J, Zhao W, Yang M, Journal of Chromatography A., 1216, 30 (2009)

[34] Purkait MK, DasGupta S, De S, Desalination, 244(1-3), 130 (2009)

[35] Purkait MK, DasGupta S, De S, J. Hazard. Mater., 137(2), 827 (2006)

[36] Miller JC, Miller JN, Statistics for Analytical Chemistry, 4th edn., Ellis Horwood, New York, 115 (1994)

[37] Minioti KS, Sakellariou CF, Thomaids NS, Analytica Chimica Acta., 583, 103 (2007)

[38] Razmara RS, Daneshfar A, Sahrai R, J. Ind. Eng. Chem., 17(3), 533 (2011)

[39] Ghoreishi SM, Behpour M, Golestaneh M, Food Chemistry., 132, 637 (2012)

[40] Nevado JJB, Flores JR, Llerena MJV, Talanta., 44, 467 (1997)