Korean Journal of Chemical Engineering, Vol.30, No.5, 1008-1012, May, 2013
Slow drift modeling and compensation in the glass electrode dynamics for the fast measurement of pH
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Glass electrodes for measuring pH in solutions show relatively fast responses with slow drifts. To design compensators to remove the drifts that hinder fast measurements of pH, a dynamic model that consists of ordinary and partial differential equations is proposed. It can explain such two-time scale responses of glass electrodes. The fitting accuracies of the proposed model are experimentally evaluated in frequency-domain and time-domain. The frequency responses obtained from the square wave responses show the fitting abilities of the proposed model, and the step responses also support this. The step responses filtered based on the proposed model show that pH measurements can be made considerably faster. The proposed model can be used to improve the dynamics of glass pH electrodes by compensating dynamic elements causing slow drifts.
- Cremer M, Z. Biol., 47, 562 (1906)
- Rad AS, Ardjmand M, Jahanshahi M, Safekordi AA, Korean J. Chem. Eng., 29(8), 1063 (2012)
- Harris DC, Exploring chemical analysis, 4th Ed., Freeman & Company (2008)
- Haugaard G, J. Phys. Chem., 45, 148 (1941)
- Cheng KL, ACS Symp. Ser., 390, 287 (1989)
- Abe Y, Maeda M, J. Electrochem. Soc., 147(2), 787 (2000)
- Buck RP, J. Electroanal. Chem., 18, 363 (1968)
- Lee JT, Lee TH, Lee SJ, Yang DR, Korean J. Chem. Eng., 26(3), 636 (2009)
- Yang DR, Lee S, Sung SW, Lee J, IEEE Sensors J., 9, 1793 (2009)
- Kohler HH, Haider C, Woelki S, Adv. Colloid Interface Sci., 114-115, 281 (2005)
- Yu GT, Chem. Phys. Lett., 384(1-3), 124 (2004)
- Gorban AN, Sargsyan HP, Wahab HA, Math. Model. Nat.Phenom., 6, 184 (2011)
- Kreyszig E, Advanced engineering mathematics, 10th Ed., Wiley, New York (2011)
- Lee J, Kim DH, Chem. Eng. J., 173(2), 644 (2011)
- Sung SW, Lee J, Lee IB, Process Control, System Identification and PID Controllers, Wiley (2009)
- Seborg DE, Edgar TF, Mellichamp DA, Process dynamics and control, 2nd Ed., Wiley, New York (2003)
- Ju SM, Kim SJ, Byeon JU, Chun DW, Sung SW, Lee JT, Korean Chem. Eng. Res., 46(5), 949 (2008)
- Lee J, Edgar TF, Chem. Eng. Sci., 65(8), 2629 (2010)