화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.30, No.4, 898-905, April, 2013
DOI10.1007/s11814-012-0180-3  Export Citation
The removal of perchlorate using amine-functionalized mesoporous anion-exchange resins with different number of ligands
Byunghwan Lee†, Sang Don Lee, and Kwang-Ho Choo1
  • Department of Chemical System Engineering, Keimyung University, 1095, Dalgubeoldaero, Dalseo-gu, Daegu 704-701, Korea
  • 1Department of Environmental Engineering, Kyungpook National University, 1370, Sankyeok-dong, Buk-gu, Daegu 702-701, Korea
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Perchlorate anion (ClO4-) in water has become an environmental issue because it can impair proper functioning of the thyroid gland. For the removal of perchlorate anions from water, adsorption using anion-exchange resins has been generally used as the most suitable method. We have prepared mesoporous anion-exchange resins via simple functionalization of amine ligands with different numbers of functional groups, and used them for the removal of perchlorate anions from aqueous solutions. The physical and chemical properties of the prepared samples were measured using nitrogen adsorption-desorption measurement, elemental analyses, X-ray diffraction, and Fourier transform infrared spectroscopy. We also investigated equilibrium isotherms for the measurement of adsorption capacities and kinetic performances of the prepared samples. The prepared materials showed fast adsorption kinetic performances, and M-3N among the prepared materials exhibited high perchlorate adsorption capacity of 175.4mg/g compared with the results of the previous reports.
Keywords:Perchlorate;Mesoporous Materials;Amine Ligands;Anion-exchange Resin
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