화학공학소재연구정보센터
Polymer Engineering and Science, Vol.53, No.1, 125-133, 2013
In situ studies on the temperature-related deformation behavior of isotactic polypropylene spherulites with uniaxial stretching: The effect of crystallization conditions
The deformation behavior of isotactic polypropylene (iPP) spherulites with uniaxial stretching was investigated at different drawing temperatures via in situ polarized optical microscope (POM) observation. The iPP spherulites were prepared by two procedures: cooled to the room temperature from melt and annealed at 135, 140, and 145 degrees C for 3 h. It was found that the crystallization conditions dominate the crystalline morphology and even the tensile properties of iPP. For iPP which crystallized during cooling progress, the spherulites were imperfect and the boundaries of the spherulites were diffuse, displaying good toughness at various drawing temperatures. For iPP annealed at high temperatures displayed the brittle fracture-modes and the crack happened between spherulites, which due to the large and perfective spherulites have thick lamellas and weak connection at interspherulitic boundary. The shape and size of the iPP spherulites formed at 140 and 145 degrees C are affected with uniaxial stretching till to the fracture of the samples at different drawing temperatures. The spherulites obtained at 135 degrees C are deformed along the drawing direction at 100 degrees C but not affected at low drawing temperatures, indicating the toughness increased with the increase of the drawing temperatures. POLYM. ENG. SCI., 2013. (c) 2012 Society of Plastics Engineers