화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.74, No.11, 2737-2746, 1999
Sequential interpenetrating polymer networks from bisphenol A based cyanate ester and bimaleimide: Properties of the neat resin and composites
Blends of varying composition of a bisphenol A based cyanate ester-viz., 2,2-bis-(4-cyanatophenyl) propane (BACY)-and a bisphenol A based bismaleimide-viz., 2,2-bis[4-(4-maleimido phenoxy) phenyl] propane (BMIP)-were cured together in a sequential manner to derive bismaleimide-triazine network. polymers. Enhancing the bismaleimide content was conducive for decreasing the tensile properties and improving both the flexural strength and fracture toughness of the cyanate ester-rich neat resin blends. Although DMA analyses of the cured blend indicated a homogeneous network for the cyanate ester dominated compositions, microphase separation occurred on enriching the blend with the bismaleimide. Addition of bismaleimide did not result in any enhancement in T-g of the blend. Interlinking of the two networks and enhancing crosslink density through coreaction with 4-cyanatophenyl maleimide impaired both the mechanical and fracture properties of the interpenetrating polymer network. (IPN), although the T-g showed an improvement. Presence of the bismaleimide was conducive for enhancing the mechanical properties of the composites of the cyanate ester rich blend, whereas a higher concentration of it led to poorer mechanical properties due to the formation of a brittle interphase. The IPNs showed reduced moisture absorption and low dielectric constant and dissipation factor, the latter properties being independent of the blend composition.