In this paper, the preparation and photophysical characterization of nanostructured cocrystals composed of B-trimesityl-N-triphenylborazine (1) and C-60 are reported. Preliminary results in the solid state show that the borazine-centered fluorescence is quenched in the cocrystal, displaying strong interchromophoric interaction in the solid state, as also shown by photoconductivity measurements.