화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.1, 240-249, January, 2013
DOI10.1016/j.jiec.2012.07.024  Export Citation
Evaluation of Fe- and Cr-containing clinoptilolite catalysts for the production of camphene from α-pinene
Murat Akgul†, Bensu Ozyagcı, and Abdulkerim Karabakan
  • Department of Chemistry, Hacettepe University, Beytepe, 06800 Ankara, Turkey
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The catalytic properties of the Cr3+- and Fe3+-loaded clinoptilolites were screened in the liquid-phase isomerization of α-pinene and the major products were found to be camphene and limonene. Selectivity to camphene was superior for the 0.7Fe-CL catalyst than those observed for the Raw-CL and 0.4Cr-CL catalyst. Over raw clinoptilolite, the proportion of limonene and other isomers reached ~ 65% while it was ~15% with 0.7Fe-CL and ~56% with 0.4Cr-CL. The results also show that the selectivity to camphene increases with increasing reaction time reaching up to about ~72% at 428 K over 0.7Fe-CL catalyst.
Keywords:Zeolite;Clinoptilolite;Camphene;α-Pinene;Isomerization
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