화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.1, 182-189, January, 2013
DOI10.1016/j.jiec.2012.07.022  Export Citation
Poly(octylmethylsiloxane)/oleyl alcohol supported liquid membrane for the pervaporative recovery of 1-butanol from aqueous and ABE model solutions
Arnel B. Beltran, Grace M. Nisola, Eleazer L. Vivas, Wonhui Cho1, and Wook-Jin Chung†
  • Energy and Environment Fusion Technology Center (E2FTC), Myongji University, San 38-2 Nam-Dong, Cheoin-Gu, Yongin City, Gyeonggi Province 449-728, South Korea
  • 1enGibbs, Hwasung-si, Bansong-dong (93-10), Gyeonggi Province 445-160, South Korea
E-mail:
Supported liquid membranes (SLM) composed of oleyl alcohol (OA) and poly(octylmethylsiloxane)(POMS) in microporous flat sheets were investigated for the pervaporation of 1-butanol. Water contact angle and partition coefficients were used to characterize the SLMs. Optimum pervaporation performance was attained at 30 wt% OA SLM wherein high separation factor (α = 279) and total flux (JT = 95.9 g/(m2 h)) were achieved from 2.5% (w/v) 1-butanol/water feed, at 60 ℃. In these conditions, 27% reduction in JT was observed when fed with model fermentation broths but remained highly selective toward 1-butanol (α = 76.4). SLM stability was demonstrated with <4% LM loss after operation.
Keywords:1-Butanol;Liquid membrane blend;Oleyl alcohol;Pervaporation;Poly(octylmethylsiloxane);Supported liquid membrane
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