Treatment characteristic of 1,4-dioxane by ozone-based advanced oxidation processes

Soon Chul Kwon; Joo Yeon Kim; Sung Min Yoon; Wisup Bae; Kyung Seok Kang; Young Woo Rhee

Journal of Industrial and Engineering Chemistry, Vol.18, No.6, 1951-1955, November, 2012

DOI10.1016/j.jiec.2012.05.010 Export Citation

Treatment characteristic of 1,4-dioxane by ozone-based advanced oxidation processes

Soon Chul Kwon, Joo Yeon Kim, Sung Min Yoon, Wisup Bae¹, Kyung Seok Kang², and Young Woo Rhee^{3, †}

Department of Applied Chemistry and Biological Engineering, Chungnam National University, 220 Gung-dong, Yusung-gu, Daejeon 305-764, Republic of Korea
¹Department of Earth and Environmental Sciences, Sejong University, Seoul 143-747, Republic of Korea
²Siontech Inc., 530 Yongsan-dong, Yusung-gu, Daejeon 305-500, Republic of Korea
³Graduate School of Green Energy Technology, Chungnam National University, 220 Gung-dong, Yusung-gu, Daejeon 305-764, Republic of Korea

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The effectiveness of different ozone-based advanced oxidation processes on the treatment of 1,4-dioxane in aqueous solution was investigated in a lab-scale reactor. The removal efficiency of 1,4-dioxane was studied under different initial pH and H2O2 concentrations. Degradation (18%) of COD was observed with the application of UV-C alone, but the degradation of COD was greatly enhanced by a combined method, O3/H2O2/UV (94%). It appears, however, that an excess amount of hydrogen peroxide in the solution retards the decomposition of 1,4-dioxane. At pH 10 and an H2O2/O3 ratio of 0.5, 1,4-dioxane in aqueous solution showed the highest degradation rate.

Keywords:1,4-Dioxane;Ozonation;Advanced oxidation process

[References]

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Balcioglu IA, Otker M, Chemosphere., 50, 85 (2003)
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Maurino VP, Minero CC, Pelizzetti E, Vincenti M, Chemosphere., 35, 2675 (2003)

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[1] Park YM, Pyo H, Park SJ, Park SK, Analytica Chimica Acta., 548, 109 (2005)

[2] Mettam GR, Adams LB, in: Jones BS, Smith RZ (Eds.), Introduction to the Electronic Age, E-Publishing, Inc., New York (2009)

[3] NICNAS, 1,4-dioxane priority Existing Chemical, 7, 93 (1998)

[4] Stefan MI, Bolton JR, Environmental Science and Technology., 32, 1588 (1998)

[5] Adams CD, Scanlan PA, Secrist ND, Environmental Science and Technology., 28, 1812 (1994)

[6] Zenker MJ, Borden RC, Barlaw MA, Environmental Engineering Science., 20, 423 (2003)

[7] Legrini O, Oliveros E, Braun AM, Chemical Reviews., 93, 671 (1993)

[8] Litter MI, Introduction to Photochemical Advanced Oxidation Processes for Water Treatment, Springer-Verlag, Berlin, 325 (2005)

[9] Benitez FJ, Acero JL, Garcia J, Leal AI, Water Research., 37, 4081 (2003)

[10] Lan BY, Nigmatullin R, Li Puma G, Water Research., 42, 2473 (2008)

[11] Lucas MS, Peres JA, Puma GL, Sep. Purif. Technol., 72(3), 235 (2010)

[12] Azbar N, Yonar T, Kestioglu K, Chemosphere., 55, 35 (2004)

[13] Jung JH, Suh H, Mohseni M, Water Research., 38, 2596 (2004)

[14] Balcioglu IA, Otker M, Chemosphere., 50, 85 (2003)

[15] Esplugas S, Gimenez J, Contreras S, Pascual E, Rodriquez M, Water Research., 36, 1034 (2002)

[16] Kwon TO, Park BB, Moon IS, Korean Chem. Eng. Res., 45(6), 648 (2007)

[17] Son HS, Choi SB, Khan E, Zoh KD, Water Research., 40, 692 (2006)

[18] Maurino VP, Minero CC, Pelizzetti E, Vincenti M, Chemosphere., 35, 2675 (2003)