Journal of Applied Polymer Science, Vol.70, No.4, 697-703, 1998
Molecular weight dependence of surface tension of polystyrene as studied by the corresponding states principle
The corresponding states correlation with the surface tension (gamma) of polymers after Patterson et al. has been modified by considering the molecular weight (M) dependence of the equation-of-state parameters, which may be estimated by either the Flory-Orwoll-Vrij (FOV) theory or the cell model (CEM). It has been found that the corresponding states principle-cum-FOV predicts the ys of polystyrene melts over a wide range of M satisfactorily. However, its CEM counterpart is rather irrelevant to the present system of interest. Indeed, the three classical linear equations proposed for the variations of gamma with M are intimately correlated with the foregoing models, and hence, facilitating the predictions of the ys of polymer end groups.