화학공학소재연구정보센터
Thin Solid Films, Vol.519, No.8, 2402-2408, 2011
High temperature oxidation behavior of CrN/AlN superlattice films
The oxidation behavior of CrN/AlN superlattice films with different bilayer periods (A), Al/(Cr + Al) ratios, and crystal structures of the AlN layer was investigated. The films were deposited using a pulsed dc closed field unbalanced magnetron sputtering system. The oxidation tests were carried out in the ambient air at elevated temperatures from 700 to 1100 C for 1 h. The changes in the crystal phase, microstructure and hardness of the films after the oxidation tests were characterized using X-ray diffraction, scanning electron microscopy and nanoindentation, respectively. When both CrN and AlN layers were in the NaCl cubic structure, the film with Lambda=3.8 nm and an Al/(Cr +Al) ratio of 0.6 exhibited a superior oxidation resistance than the film with Lambda=12.4 nm and an Al/(Cr +Al) ratio of 0.19. The film with Lambda=3.8 nm maintained the nanolayered structure with an oxidation temperature up to 1000 C by the protection of a thin and dense X-ray amorphous oxide layer. In contrast, when the AlN layers were in the Wurzite hexagonal structure, the film with Lambda=22.5 nm and an Al/(Cr +Al) ratio of 0.67 exhibited poor oxidation resistance. The film lost the superlattice structure at 800 degrees C and was completely oxidized at 1000 T due to the formation of a porous crystalline oxide layer on the surface. Published by Elsevier B.V.