화학공학소재연구정보센터
Thin Solid Films, Vol.517, No.17, 5161-5165, 2009
Optical investigations of multi-dimensional ZnO hybrid structures
The authors report on the optical properties of multi-dimensional ZnO hybrid structures. consisting of film (2D)/nanorods (1D)/sapphire substrate (2D), grown by metalorganic chemical vapor deposition (MOCVD). Photoluminescence investigations reveal that the sample with top layer grown at a decreased growth temperature of 240 degrees C and increased reactor pressure of 5 Torr exhibits superior emission properties. The presence of strong E(2)(high) optical phonon mode at 438.5 cm(-1) in the visible micro-Raman spectra demonstrates the wurtzite nature of ZnO. Although the ultraviolet Raman scattering measurements of the hybrid structures reveal the presence of in-plane tensile stress in the top ZnO layer. the sample with the improved emission performance shows the release of tensile stress. (c) 2009 Elsevier B.V. All rights reserved.