화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.95, No.12, 3592-3595, 2011
Improved LDSE processing for the avoidance of overplating yielding 19.2% efficiency on commercial grade crystalline Si solar cell
A record in laser doped selective emitter (LDSE) solar cells with an efficiency eta = 19.2% is reported. In this study, we investigate the effect of SiN(x) films for laser doped selective emitter solar cells with plated front contacts. It is observed that the condition of processes such as silicon nitride and laser doping (LD) is of critical importance prior to light induced plating. If these processes are not performed optimally, localized shunts may form during the light induced plating (LIP) process that then inhibit plating in the surrounding areas. In the previous work an efficiency of 18.3% has been achieved, even though the fill factor was only 74.2% and the cell suffered from additional shunting and shading losses due to overplating. However, in this work, we demonstrate that with the optimization of the PECVD SiN(x) and metallization processes, cells have reached efficiencies of more than 19% on commercial grade p-type CZ Si substrates. (C) 2011 Elsevier B.V. All rights reserved.