Sunlight irradiating the surface of the Earth represents a maximum input available for a solar catalytic process of 50 W-UV m(-2). Reticulated macroporous foams, which exhibit an open three-dimensional network structures, were studied in order to make good use of UV rays to break down molecules. The aim was to assess the apparent quantum yield of the media used for the photocatalysis. The optical properties of the medium were ascertained using an experimental optical setup. The measurement of the degradation kinetics was carried out on 2-4 dichlorophenol. The main objective of the present study was to determine the most favorable structure for use of UV rays and to understand what structure should be developed to increase the efficiency of the medium. (C) 2011 Elsevier B.V. All rights reserved.