Thickness-Insensitive Spectrally Selective (TISS) paint coatings were made of fluoropolymer resin binder (Lumiflon (LF), Asahi Glass Co., Ltd., Japan) and their water- and oil-repellent properties were obtained (contact angle: theta(water)similar to 150 degrees, theta(n-hexadecane)similar to 55 degrees) by the addition of Polyhedral Oligomeric Silsesquioxane (POSS) characterized by amino (AP), isooctyl (IO) and perfluoro (PF) groups (i.e. AP(2)IO(4)PF(2)) attached on the silsesquioxane cube (-SiO(3/2))(8). Paint dispersions were made by modifying of black spinel pigment with trisilanol isobutyl (IB(7)T(7)(OH)(3)) POSS dispersant and with a single-capped silane isobutyltrimethoxysilane (IBTMS). Infrared and (29)Si NMR spectra measurements were used for the identification of the structural characteristic of the corresponding POSS compounds. Surface free energy values of the pure cross-linked (no pigment added) LF binder which was determined from the measured contact angles for water, diiodomethane and formamide revealed the gamma(tot) value of the LF unpigmented resin with added AP(2)IO(4)PF(2) T(8) POSS was about 16.4 mN/m, which led to the theta(water)similar to 110 degrees indicating enhancement of the hydrophobicity of the pure LF resin binder (theta(water)similar to 89 degrees). SEM micrographs, which were used for the assessment of the TISS paint coating surface morphology confirmed the beneficial dispersive effect of IB(7) T(7)(OH)(3) dispersant as compared to the IBTMS silane. The presence of large Aluminium flake pigment and finely ground black pigment led to the formation of TISS paint Coating Surface, which exhibited bi-hierarchical roughness, resulting in water sliding angles of less than 10 degrees, indicating the possible self-cleaning effect (theta(water) > 150 degrees and theta(n-hexadecane)similar to 55 degrees). The use of POSS dispersant and POSS low surface energy additive also enhanced spectral selectivity, which became the highest known so far for the black TISS paint coatings (e(T)similar to 0.24 and a(s)similar to 0.93). The use of simple silane IBTMS dispersant even in the presence of the AP(2)IO(4)PF(2) T(8) POSS did not lead to the oil-repellent effect confirmed by spreading of n-hexadecane on the surface of the corresponding TISS paint coating. (C) 2009 Elsevier B.V. All rights reserved.