Solar Energy Materials and Solar Cells, Vol.72, No.1-4, 221-221, 2002
Crystalline silicon thin films with porous Si backside reflector (abstract only)
Thin film crystalline Si solar cells on cheap Si-based substrates have a large potential in PV technology. optical light confinement is a very crucial point of such thin film structures. Porous Si (PS) as a perfect light diffuser could be used as a backside reflector if its multi-layer structure would be preserved during the deposition of a thin Si film. That is why low-energy plasma enhanced chemical vapor deposition (LEPECVD) is chosen to deposit a thin Si film on a PS multilayer structure at low temperature and a high deposition rate. This technique allows one to deposit a Si film with an epitaxial quality on the top of PS without destroying its multilayer structure as revealed by high-resolution X-ray diffraction and cross-sectional transmission electron microscopy (TEM). The epilayers of 10mum are grown at very high deposition rate (around 3 nm/s) at 590degreesC. TEM-analysis reveals that during the deposition a high density of defects forms at the interface PS/epi-Si and spreads through the whole epilayer, The defect density is decreased when the deposition temperature is increased to 645degreesC. LEPECVD appears to be an appropriate deposition technique to grow thin Si films on cheap Si based substrates with PS reflector. (C) 2002 Elsevier Science B.V. All rights reserved.