Blends of native corn starch and poly(ethylene-co-vinyl alcohol) (EVOH), with starch : EVOH ratios of 1 : 1 (SE-50) and 2 : 1 (SE-67A, SE-67B), were processed into blown films. SE-67A had a higher glycerol and water content and was processed at 5 degrees C higher than was SE-67B. The films were conditioned to various moisture contents by equilibrating at a constant relative humidity and by oven drying at 41 degrees C. Equilibrium moisture content, which ranged from 2 to 11%, increased with increasing starch content at a given relative humidity. Mechanical properties depended strongly on starch and moisture content as well as on processing history. The extension to break of SE-50 was only about one-third that of EVOH, while that of the 2 : 1 blends was even lower. SE-67A exhibited a higher extension to break, lower tensile strength and modulus, and greater moisture sensitivity than those of SE-67B. Differential scanning calorimetry and dynamic mechanical analysis revealed evidence of interactions between starch and EVOH, probably indicative of extensive intermixing but not necessarily miscibility. Scanning electron micrographs of fracture surfaces revealed extensive differences in texture with microcracking in SE-50 and SE-67A. The combination of the analytical results provide a basis for explaining many aspects of the mechanical behavior including the marked difference in properties between SE-67A and SE-67B.