Petroleum Chemistry, Vol.42, No.4, 261-264, 2002
The kinetics and mechanism of interaction of substituted arylthiocarbamides and their metal complexes with cumene hydroperoxide
The kinetics and mechanism of the reaction of substituted thiocarbamides and their metal complexes with cumene hydroperoxide were studied. It was found that heterolytic route of the reaction is predominant. The metal complexes turned out to be more active in cumene hydroperoxide decomposition than the parent arylthiocarbamides involved in their composition.