화학공학소재연구정보센터
Plasma Chemistry and Plasma Processing, Vol.29, No.1, 69-78, 2009
Determination of the Number of OH Radicals in EB-Irradiated Humid Gases Using Oxidation of CO
Electron beam (EB) technology has an advantage for treating dilute environmental pollutants in gases due to high-density population of active species such as radicals and atoms. In general, OH radicals play an important role of initiating the decomposition and removal of such pollutants. It is quite important to understand the behavior of OH radical production for the development of efficient decomposition/removal processes and the comparison with other purification methods. The number of OH radicals produced in humid N(2) at doses of 2.0-10.0 kGy with dose rates of 0.17-2.55 kGy/s under 1-MeV EB irradiation was indirectly determined using an index of oxidation of CO to CO(2), which has been used in atmospheric chemistry. An experiment under conditions where all OH radicals produced react with CO demonstrated that the concentration of CO(2) increased linearly with doses of 0-10 kGy, and the G(OH) was estimated as 4.90.