A novel reactor design, sampling probe and wet collection system were used to investigate the combined effects of plasma operating parameters and particle collection mechanisms on the synthesis of CeO2 particles from liquid precursors. The sampling of particles in-flight and the collection of particles at several reactor regions were used to provide experimental evidence of particle size at different reactor locations at various plasma operating conditions, i.e., power and plasma gas flow rates. This information provided a picture of how CeO2 particles were formed and how these particles were collected in various locations. The effect of adding water-soluble fuels (alanine and glycine) to the original cerium nitrate solutions was also investigated. Fuel addition decreased the temperature of CeO2 formation by acting as a local heat source as a result of fuel auto-ignition. Photographs of the particles in-flight were taken using a fast speed CCD camera.