Grafting of poly(acrylic acid) onto commercial polypropylene films following irradiation by gamma-rays was carried out in order to improve their surface properties. The amount of grafting with the irradiation dose was found not to follow the expected linear dependence as it is normally observed for polypropylene films prepared in laboratory amounts. We therefore analyzed the influence of the industrial manufacture process in terms of orientation of the film and addition of antioxidants by determining the peroxide surface density and the extent of grafting therefrom. The unoriented polypropylene film presented the highest peroxide concentration and was thus the most adapted material for successful grafting. Whereas phenol antioxidants limit the peroxide formation and thus must be removed from the film for grafting, the thickness of the chemical modification can be controlled by means of phosphites. Atomic force microscopy and wettability measurements showed that the grafted poly(acrylic acid) was heterogeneously distributed on the surface of the film, explaining the observed low reproducibility of the grafting reaction. However, we observed that the polarity of the surface was increased by the grafting.