화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.55, No.6, 851-856, 1995
Radiopaque Epoxy-Resins
Transparent, X-ray contrast (radiopaque) epoxy resins were obtained by dissolving up to 25 wt % triphenylbismuth in the commercial epoxy resin prepolymers EPON-815, DER-330, DER-383, and DEN-431 which were then hardened with diethylenetriamine. The radiopacities of the mixtures were found to be proportional to the molar concentration of the radiopaque additive. The systems follow the relationship, R = R(o) + (R(a) - R(o))(V) over bar(a) M(a) where R, R(o), and R(a) are the radiopacities of the mixture, the pure epoxy resin, and triphenylbismuth, respectively (expressed in mm aluminum/mm resin); M(a) and (V) over bar(a) denote the molar concentration and molar volume of the bismuth compound. R(a) for triphenylbismuth was found to be 7.4 +/- 0.2 mm Al/mm resin; the average value of R(o) for the four epoxies equals 0.16 +/- 0.1 mm Al/mm resin. The amount of amine required to harden the radiopaque resins was far less for the epoxy novolac resin DEN-431 than for the three bisphenol-A based epoxies. The concentration of triphenylbismuth required to impart a radiopacity equivalent to that of aluminum measures 14.6 wt % in EPON-815, 14.8 wt % in DER-330, 14.9 wt % in DER-383, and 15.9 wt % in DEN-431. The radiopaque resins remain transparent indefinitely, even when exposed to water.