Materials Research Bulletin, Vol.47, No.8, 2008-2011, 2012
New natively textured surface Al-doped ZnO-TCOs for thin film solar cells via magnetron sputtering
Natively textured surface aluminum doped zinc oxide (ZnO:Al) thin films were directly deposited via pulsed direct current (DC) reactive magnetron sputtering on glass substrates. During the reactive sputtering process, the oxygen gas flow rate was varied from 8.5 sccm to 11.0 sccm. The influences of oxygen flow rate on the structural, electrical and optical properties of naturally textured ZnO:Al TCO thin films with milky surface were investigated in detail. Gradual oxygen growth (GOG) technique was developed in the reactive sputtering process for textured ZnO:Al thin films. The light-scattering ability and optical transmittance of the natively textured ZnO:Al TCO thin films can be improved through gradual oxygen growth method while maintaining a low sheet resistance. Typical natively textured ZnO:Al TCO thin film with crater-like surface exhibits low sheet resistance (R-s similar to 4 Omega), high transmittance (T-a > 85%) in visible optical region and high haze value (12.1%). (c) 2012 Elsevier Ltd. All rights reserved.
Keywords:Thin films;Semiconductors;Sputtering;Crystal growth;Electrical properties;Surface properties