Flower-like Ni-3(NO3)(2)(OH)(4) was successfully synthesized by a facile solvothermal method. The microstructure and surface morphology of prepared Ni-3(NO3)(2)(OH)(4) were physically characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and transmission electron microscope crew. The electrochemical properties studies were carried out using cyclic voltammetry (CV), chronopotentiometry technology and AC impedance spectroscopy, respectively. The results indicate that the flower-like structure has a profound impact on electrode performance at high discharge capacitance. A maximum specific capacitance of 2212.5 F g(-1) at the current density of 5 mA could be achieved, suggesting its potential application in electrode material for secondary batteries and electrochemical capacitors. Furthermore, the effects of Ni(NO3)(2)center dot 6H(2)O concentration and temperature on the microstructure and specific capacitance of prepared Ni-3(NO3)(2)(OH)(4) have also been systematically studied. The results show that flower-like structure can be formed when the concentration is appropriate, while the temperature has just little effect on its electrochemical properties. (C) 2012 Elsevier Ltd. All rights reserved.