ZSM-23/ZSM-22 intergrowth zeolite with fixed proportion of 60%ZSM-23/40%ZSM-22 has been synthesized with a novel dual-template strategy. The products were characterized by X-ray diffraction and scanning electron microscopy. Dimethylamine and diethylamine were used together as a dual-template system. The molar ratio of diethylamine to dimethylamine, which was changed with the type of aluminum Source, was the key factor for the synthesis of intergrowth zeolites. A molar ratio of diethylamine to dimethylamine of 1:24 could result in an ZSM-23/ZSM-22 intergrowth zeolite if aluminum sulfate was used as aluminum source, whereas a molar ratio of diethylamine to dimethylamine of 1:12 was required to get an ZSM-23/ZSM-22 intergrowth zeolite if sodium metaaluminate was used. Furthermore, fluoride anion could be involved in the process as a crystallization promoter. (C) 2009 Elsevier Ltd. All rights reserved.