Densities and viscosities at (298.15, 308.15, and 318.15) K are presented as a function of mixture composition for the binary mixtures of propylene glycol monomethyl ether with methacrylic acid, benzyl methacrylate, and 2-hydroxyethyl methacrylate. From the experimental data, the excess molar volumes and viscosity deviations have been calculated. These results have been correlated with the Redlich-Kister type polynomial to derive the coefficients and standard deviation. McAllister's three-body and four-body interaction models were also used to correlate the kinematic viscosities. These model's parameters were treated to be temperature-dependent.