화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.50, No.6, 2106-2111, 2005
Henry's law constants and infinite dilution activity coefficients of propane, propene, butane, 2-methylpropane, 1-butene, 2-methylpropene, trans-2-butene, cis-2-butene, 1,3-butadiene, dimethyl ether, chloroethane, and 1,1-difluoroethane in 2-methyl-3-buten-2-ol and 3-methyl-3-buten-1-ol
Henry's law constants and infinite dilution activity coefficients of propane, propene, butane, 2-methylpropane, 1-butene, 2-methylpropene, trans-2-butene, cis-2-butene, 1,3-butadiene, dimethyl ether, chloroethane, and 1,1-difluoroethane in 2-methyl-3-buten-2-ol and 3-methyl-3-buten-1-ol in the temperature range of (250 to 330) K were measured by a gas stripping method, and partial molar excess enthalpies were calculated from the activity coefficients. The estimated uncertainties are about 2 % for the Henry's law constants and 3 % for the infinite dilution activity coefficients. In general the Henry's law constants followed the order of increasing Henry's law constant with decreases in the normal boiling point temperature of the liquefied gas except for 1,3-butadiene, and the partial molar excess enthalpies of gases followed the order of increasing partial molar excess enthalpy with decreases of the polarity of the gases except for chloroethane and 1,1-difluoroethane.